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(E)-2-[(2,4-Dichloro-phen-yl)imino-meth-yl]benzene-1,4-diol monohydrate.

ABSTRACT: The title compound, C(13)H(9)Cl(2)NO(2)·H(2)O, represents a Schiff base which adopts the phenol-imine tautomeric form in the solid state. The mol-ecule is approximately planar (r.m.s. deviation 0.0818?Å), and the dihedral angle between the two aromatic rings is 7.46?(12)°. An O-H?N inter-action generates an S(6) ring. In the crystal, mol-ecules are linked by inter-molecular O-H?O hydrogen bonds involving the solvent water mol-ecule, forming chains.

SUBMITTER: Sahin ZS

PROVIDER: S-EPMC2972111 | biostudies-literature | 2009 Nov

REPOSITORIES: biostudies-literature

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(E)-2-[(2,4-Dichloro-phen-yl)imino-meth-yl]benzene-1,4-diol monohydrate.

Sahin Zarife Sibel ZS Gūmūş Sūmeyye S Macit Mustafa M Işık Samil S

Acta crystallographica. Section E, Structure reports online 20091107 Pt 12

The title compound, C(13)H(9)Cl(2)NO(2)·H(2)O, represents a Schiff base which adopts the phenol-imine tautomeric form in the solid state. The mol-ecule is approximately planar (r.m.s. deviation 0.0818 Å), and the dihedral angle between the two aromatic rings is 7.46 (12)°. An O-H⋯N inter-action generates an S(6) ring. In the crystal, mol-ecules are linked by inter-molecular O-H⋯O hydrogen bonds involving the solvent water mol-ecule, forming chains. ...[more]

PMID: 21578759

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