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2,3-O-Isopropyl-idene-3-C-phenyl-erythrofuran-ose.


ABSTRACT: The title compound, C(13)H(16)O, comprises two fused five-membered rings. Each ring has an envelope conformation, with the ether O atom in the furan-ose ring, and the CMe(2) atom in the acetonide ring as the flap atoms. In the crystal, centrosymmetrically related mol-ecules associate via hydr-oxy-ether O-H?O hydrogen bonds and the resulting dimers are linked into a supra-molecular chain with a flattened topology via C-H?O(hydr-oxy) contacts, and aligned in the a-axis direction.

SUBMITTER: Robinson TV 

PROVIDER: S-EPMC2972136 | biostudies-literature | 2009 Nov

REPOSITORIES: biostudies-literature

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2,3-O-Isopropyl-idene-3-C-phenyl-erythrofuran-ose.

Robinson Tony V TV   Taylor Dennis K DK   Tiekink Edward R T ER  

Acta crystallographica. Section E, Structure reports online 20091121 Pt 12


The title compound, C(13)H(16)O, comprises two fused five-membered rings. Each ring has an envelope conformation, with the ether O atom in the furan-ose ring, and the CMe(2) atom in the acetonide ring as the flap atoms. In the crystal, centrosymmetrically related mol-ecules associate via hydr-oxy-ether O-H⋯O hydrogen bonds and the resulting dimers are linked into a supra-molecular chain with a flattened topology via C-H⋯O(hydr-oxy) contacts, and aligned in the a-axis direction. ...[more]

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