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7-Bromo-1-methyl-sulfinyl-2-phenyl-naphtho[2,1-b]furan.

ABSTRACT: In the title compound, C(19)H(13)BrO(2)S, the O atom and the methyl group of the methyl-sulfinyl substituent lie on opposite sides of the plane of the naphthofuran unit. The phenyl ring is rotated out of the naphthofuran plane, making a dihedral angle of 42.2?(1)°. The crystal structure is stabilized by two inter-molecular C-H?? inter-actions, and by non-classical inter-molecular C-H?O and C-H?Br hydrogen bonds.

SUBMITTER: Choi HD

PROVIDER: S-EPMC2977132 | biostudies-literature | 2009 Jul

REPOSITORIES: biostudies-literature

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7-Bromo-1-methyl-sulfinyl-2-phenyl-naphtho[2,1-b]furan.

Choi Hong Dae HD Seo Pil Ja PJ Son Byeng Wha BW Lee Uk U

Acta crystallographica. Section E, Structure reports online 20090722 Pt 8

In the title compound, C(19)H(13)BrO(2)S, the O atom and the methyl group of the methyl-sulfinyl substituent lie on opposite sides of the plane of the naphthofuran unit. The phenyl ring is rotated out of the naphthofuran plane, making a dihedral angle of 42.2 (1)°. The crystal structure is stabilized by two inter-molecular C-H⋯π inter-actions, and by non-classical inter-molecular C-H⋯O and C-H⋯Br hydrogen bonds. ...[more]

PMID: 21583634

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7-Bromo-2-methyl-1-tosyl-naphtho[2,1-b]furan.

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