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(E)-3-Bromo-N'-(4-hydr-oxy-3-nitro-benzyl-idene)benzohydrazide.

ABSTRACT: The title compound, C(14)H(10)BrN(3)O(4), was synthesized by the reaction of 4-hydr-oxy-3-nitro-benzaldehyde with an equimolar quantity of 3-bromo-benzohydrazide in methanol. The mol-ecule displays an E configuration about the C=N bond. The dihedral angle between the two benzene rings is 4.6?(2)°. The nitro group is almost coplanar with the attached benzene ring [dihedral angle = 4.7?(2)°]. In the crystal structure, mol-ecules are linked into sheets parallel to (100) by inter-molecular N-H?O, O-H?N and O-H?O hydrogen bonds.

SUBMITTER: Cao GB

PROVIDER: S-EPMC2977221 | biostudies-literature | 2009

REPOSITORIES: biostudies-literature

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(E)-3-Bromo-N'-(4-hydr-oxy-3-nitro-benzyl-idene)benzohydrazide.

Cao Guo-Biao GB Wang Xiao-Ya XY

Acta crystallographica. Section E, Structure reports online 20090701 Pt 8

The title compound, C(14)H(10)BrN(3)O(4), was synthesized by the reaction of 4-hydr-oxy-3-nitro-benzaldehyde with an equimolar quantity of 3-bromo-benzohydrazide in methanol. The mol-ecule displays an E configuration about the C=N bond. The dihedral angle between the two benzene rings is 4.6 (2)°. The nitro group is almost coplanar with the attached benzene ring [dihedral angle = 4.7 (2)°]. In the crystal structure, mol-ecules are linked into sheets parallel to (100) by inter-molecular N-H⋯O, O- ...[more]

PMID: 21583442

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