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Trans-Diaqua-bis[5-carb-oxy-2-(3-pyrid-yl)-1H-imidazole-4-carboxyl-ato-?N,O]iron(II).

ABSTRACT: In the title complex, [Fe(C(10)H(6)N(3)O(4))(2)(H(2)O)(2)], the Fe(II) atom is located on an inversion centre and is trans-coordinated by two N,O-bidentate 5-carb-oxy-2-(3-pyrid-yl)-1H-imidazole-4-carb-oxy-l-ate ligands and two water mol-ecules, defining a distorted octa-hedral environment. A two-dimensional network of N-H?O and O-H?O hydrogen bonds extending parallel to (110) helps to stabilize the crystal packing.

SUBMITTER: Liu W

PROVIDER: S-EPMC2977312 | biostudies-literature | 2009 Jul

REPOSITORIES: biostudies-literature

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trans-Diaqua-bis[5-carb-oxy-2-(3-pyrid-yl)-1H-imidazole-4-carboxyl-ato-κN,O]iron(II).

Liu Wei W Zhang Gang G Li Xia X Wu Ben-Lai BL Zhang Hong-Yun HY

Acta crystallographica. Section E, Structure reports online 20090718 Pt 8

In the title complex, [Fe(C(10)H(6)N(3)O(4))(2)(H(2)O)(2)], the Fe(II) atom is located on an inversion centre and is trans-coordinated by two N,O-bidentate 5-carb-oxy-2-(3-pyrid-yl)-1H-imidazole-4-carb-oxy-l-ate ligands and two water mol-ecules, defining a distorted octa-hedral environment. A two-dimensional network of N-H⋯O and O-H⋯O hydrogen bonds extending parallel to (110) helps to stabilize the crystal packing. ...[more]

PMID: 21583390

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