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Tetra-aqua-(1,10-phenanthroline)nickel(II) 3,6-dicarboxy-bicyclo-[2.2.2]oct-7-ene-2,5-dicarboxyl-ate.

ABSTRACT: In the title compound, [Ni(C(12)H(8)N(2))(H(2)O)(4)](C(12)H(10)O(8)), the Ni(II) ion is six-coordinated by two N atoms from one phenanthroline ligand and by the O atoms of four water mol-ecules in a distorted octa-hedral geometry. In the crystal, inter-molecular O-H?O hydrogen bonds form an extensive three-dimensional network, which consolidates the crystal packing.

SUBMITTER: Liu YY 

PROVIDER: S-EPMC2977452 | biostudies-literature | 2009

REPOSITORIES: biostudies-literature

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Tetra-aqua-(1,10-phenanthroline)nickel(II) 3,6-dicarboxy-bicyclo-[2.2.2]oct-7-ene-2,5-dicarboxyl-ate.

Liu Yun-Yu YY   Wang Tian-Hui TH   Wang Zhi-Hao ZH   Zhuo Yu-Jiang YJ   Li Xing-Qi XQ  

Acta crystallographica. Section E, Structure reports online 20090722 Pt 8

In the title compound, [Ni(C(12)H(8)N(2))(H(2)O)(4)](C(12)H(10)O(8)), the Ni(II) ion is six-coordinated by two N atoms from one phenanthroline ligand and by the O atoms of four water mol-ecules in a distorted octa-hedral geometry. In the crystal, inter-molecular O-H⋯O hydrogen bonds form an extensive three-dimensional network, which consolidates the crystal packing. ...[more]

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