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(5,5'-Dicarboxy-biphenyl-2,2'-dicarboxyl-ato-?O,O)bis-(1,10-phenanthroline-?N,N')zinc(II) dihydrate.


ABSTRACT: In the title compound, [Zn(C(16)H(8)O(8))(C(12)H(8)N(2))(2)]·2H(2)O, the Zn(II) atom is located on a twofold rotation axis and is six-coordinated by two O atoms from a 5,5'-dicarboxy-biphenyl-2,2'-dicarboxyl-ate ligand and four N atoms from two 1,10-phenanthroline mol-ecules in a distorted octa-hedral geometry. The crystal structure involves O-H?O hydrogen bonds.

SUBMITTER: Chen RZ 

PROVIDER: S-EPMC2961799 | biostudies-other | 2008 Jun

REPOSITORIES: biostudies-other

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(5,5'-Dicarboxy-biphenyl-2,2'-dicarboxyl-ato-κO,O)bis-(1,10-phenanthroline-κN,N')zinc(II) dihydrate.

Chen Rui-Zhan RZ   Guo Fei-Jun FJ   Meng Fan-Lei FL  

Acta crystallographica. Section E, Structure reports online 20080607 Pt 7


In the title compound, [Zn(C(16)H(8)O(8))(C(12)H(8)N(2))(2)]·2H(2)O, the Zn(II) atom is located on a twofold rotation axis and is six-coordinated by two O atoms from a 5,5'-dicarboxy-biphenyl-2,2'-dicarboxyl-ate ligand and four N atoms from two 1,10-phenanthroline mol-ecules in a distorted octa-hedral geometry. The crystal structure involves O-H⋯O hydrogen bonds. ...[more]

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