Ontology highlight
ABSTRACT:
SUBMITTER: Wang ZH
PROVIDER: S-EPMC2977466 | biostudies-literature | 2009 Jul
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20090711 Pt 8
In the title compound, C(32)H(16)S(4)·1.5C(6)H(6), the substituted cyclo-octa-tetra-ene (COT) ring compound has approximate local D(2) point symmetry of the so-called 'saddle' form: the dihedral angles between neighboring benzo[b]thio-phene units are 61.33 (4), 61.61 (4), 56.443 (14) and 58.32 (4)°. The short distance [3.545 (1) Å] between an S atom and the centroid of a benzene ring in a neighboring mol-ecule may indicate S⋯π inter-actions in the crystal. ...[more]