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Bis[4-(dimethyl-amino)pyridinium] tetra-bromidocadmate(II) monohydrate.

ABSTRACT: The Cd atom in the hydrated title salt, (C(7)H(11)N(2))(2)[CdBr(4)]·H(2)O, exists in an approximately tetra-hedral coordination geometry, with Br-Cd-Br angles in the range 105.52?(3)-111.50?(3)°. The cation, anion and water mol-ecule inter-act by O-H?Br, N-H?Br and N-H?O hydrogen bonds, forming a linear chain structure running along the a axis.

SUBMITTER: Lo KM

PROVIDER: S-EPMC2977606 | biostudies-literature | 2009 Apr

REPOSITORIES: biostudies-literature

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Bis[4-(dimethyl-amino)pyridinium] tetra-bromidocadmate(II) monohydrate.

Lo Kong Mun KM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20090425 Pt 5

The Cd atom in the hydrated title salt, (C(7)H(11)N(2))(2)[CdBr(4)]·H(2)O, exists in an approximately tetra-hedral coordination geometry, with Br-Cd-Br angles in the range 105.52 (3)-111.50 (3)°. The cation, anion and water mol-ecule inter-act by O-H⋯Br, N-H⋯Br and N-H⋯O hydrogen bonds, forming a linear chain structure running along the a axis. ...[more]

PMID: 21583792

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