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Bis[4-(dimethyl-amino)-pyridinium] bis-[4-(dimethyl-amino)-pyridine-?N (1)]tetra-kis-(thio-cyanato-?N)manganate(II).

ABSTRACT: In the crystal structure of the title compound, (C7H11N2)2[Mn(NCS)4(C7H10N2)2], the manganese(II) cations are coordinated by four N-bonded thio-cyanate anions and two N-bonded 4-(dimethyl-amino)-pyridine ligands into discrete complex dianions. For charge balance, two 4-(dimethylamino)pyridine counter cations are present, which do not coordinate to the metal cation. The asymmetric unit consists of one manganese(II) cation, four thio-cyanate anions and two 4-(dimethyl-amino)-pyridine ligands, as well as two protonated 4-(dimethyl-amino)-pyridinium cations. The discrete complex anions are connected to the non-coordinating pyridinium cations by weak N-H?S hydrogen-bonding inter-actions.

SUBMITTER: Wohlert S 

PROVIDER: S-EPMC3588772 | biostudies-literature | 2012 Dec

REPOSITORIES: biostudies-literature

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Bis[4-(dimethyl-amino)-pyridinium] bis-[4-(dimethyl-amino)-pyridine-κN (1)]tetra-kis-(thio-cyanato-κN)manganate(II).

Wöhlert Susanne S   Jess Inke I   Näther Christian C  

Acta crystallographica. Section E, Structure reports online 20121124 Pt 12

In the crystal structure of the title compound, (C7H11N2)2[Mn(NCS)4(C7H10N2)2], the manganese(II) cations are coordinated by four N-bonded thio-cyanate anions and two N-bonded 4-(dimethyl-amino)-pyridine ligands into discrete complex dianions. For charge balance, two 4-(dimethylamino)pyridine counter cations are present, which do not coordinate to the metal cation. The asymmetric unit consists of one manganese(II) cation, four thio-cyanate anions and two 4-(dimethyl-amino)-pyridine ligands, as w  ...[more]

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