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Methyl 5-bromo-2-[meth-yl(methyl-sulfon-yl)amino]benzoate.

ABSTRACT: The title compound, C(10)H(12)BrNO(4)S, is an inter-mediate in the synthesis of benzothia-zine. The planar methyl ester group (maximum deviation is 0.0065?Å) is oriented at a dihedral angle of 39.09?(13)° with respect to the aromatic ring. In the crystal structure, weak inter-molecular C-H?O inter-actions link the mol-ecules into centrosymmetric dimers, through R(2) (2)(10) ring motifs.

SUBMITTER: Shafiq M

PROVIDER: S-EPMC2977655 | biostudies-literature | 2009 Apr

REPOSITORIES: biostudies-literature

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Methyl 5-bromo-2-[meth-yl(methyl-sulfon-yl)amino]benzoate.

Shafiq Muhammad M Tahir M Nawaz MN Khan Islam Ullah IU Arshad Muhammad Nadeem MN Khan Muneeb Hayat MH

Acta crystallographica. Section E, Structure reports online 20090402 Pt 5

The title compound, C(10)H(12)BrNO(4)S, is an inter-mediate in the synthesis of benzothia-zine. The planar methyl ester group (maximum deviation is 0.0065 Å) is oriented at a dihedral angle of 39.09 (13)° with respect to the aromatic ring. In the crystal structure, weak inter-molecular C-H⋯O inter-actions link the mol-ecules into centrosymmetric dimers, through R(2) (2)(10) ring motifs. ...[more]

PMID: 21583998

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