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2-Chloro-N-(3,5-dimethyl-phen-yl)acetamide.

ABSTRACT: The conformation of the C=O bond in the structure of the title compound, C(10)H(12)ClNO, is anti to the N-H bond and to the C-Cl bond in the side chain in all four independent mol-ecules comprising the asymmetric unit. In the crystal, inter-molecular N-H?O hydrogen bonds link the mol-ecules into supra-molecular chains.

SUBMITTER: Gowda BT

PROVIDER: S-EPMC2977723 | biostudies-literature | 2009 Apr

REPOSITORIES: biostudies-literature

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2-Chloro-N-(3,5-dimethyl-phen-yl)acetamide.

Gowda B Thimme BT Foro Sabine S Terao Hiromitsu H Fuess Hartmut H

Acta crystallographica. Section E, Structure reports online 20090418 Pt 5

The conformation of the C=O bond in the structure of the title compound, C(10)H(12)ClNO, is anti to the N-H bond and to the C-Cl bond in the side chain in all four independent mol-ecules comprising the asymmetric unit. In the crystal, inter-molecular N-H⋯O hydrogen bonds link the mol-ecules into supra-molecular chains. ...[more]

PMID: 21583859

Similar Datasets

2,2-Dichloro-N-(3,5-dimethyl-phen-yl)-acetamide.

Project description:The structure of the title compound, C(10)H(11)Cl(2)NO, resembles those of 2,2-dichloro-N-phenyl-acetamide, 2,2-dichloro-N-(2-methyl-phen-yl)acetamide, 2,2-dichloro-N-(3-methyl-phen-yl)-acetamide, 2,2-dichloro-N-(4-methyl-phen-yl)acetamide, N-(3,5-dimethyl-phen-yl)acetamide and other acetanilides, with similar bond parameters. The mol-ecules in the title compound are linked into infinite chains through N-H?O and C-H?O hydrogen bonding.

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2-Chloro-N-(2,6-dimethyl-phen-yl)acetamide.

Project description:The crystal structure of the title compound (26DMPCA), C(10)H(12)ClNO, is closely related to those of side-chain-unsubstituted N-(2,6-dimethyl-phen-yl)acetamide and side-chain-substituted 2,2,2-trichloro-N-(2,6-dimethyl-phen-yl)-acet-amide and N-(2,6-dimethyl-phen-yl)-2,2,2-trimethylacet-amide, with slightly different bond parameters. The mol-ecules in 26DMPCA are linked into chains through N-H?O hydrogen bonding.

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2-Chloro-N-(2,4-dimethyl-phen-yl)acetamide.

Project description:The conformation of the N-H bond in the structure of the title compound, C(10)H(12)ClNO, is syn to the ortho methyl group, similar to that observed with respect to the meta methyl group in 2-chloro-N-(3-methyl-phen-yl)acetamide and the ortho-chloro group in 2-chloro-N-(2-chloro-phen-yl)acetamide. The geometric parameters are similar to those of other acetanilides. The mol-ecules are linked into chains through inter-molecular N-H?O hydrogen bonds.

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2-Chloro-N-(3,4-dimethyl-phen-yl)acetamide.

Project description:The conformation of the C=O bond in the structure of the title compound, C(10)H(12)ClNO, is anti to the N-H bond and to the methyl-ene H atoms in the side chain in both the independent mol-ecules comprising the asymmetric unit. However, the conformation of the N-H bond is syn to the meta-methyl substituent in the aromatic ring of one of the mol-ecules and anti in the other mol-ecule. The two independent mol-ecules are linked through inter-molecular N-H?O hydrogen bonding into chains parallel to the b axis.

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2-Chloro-N-(3,5-dimethyl-phen-yl)benzamide.

Project description:In the structure of the the title compound, C(15)H(14)ClNO, the N-H and C=O bonds are trans to each other and the amide O atom is anti to the ortho-Cl atom in the benzoyl ring. The amide group makes dihedral angles of 61.2?(6) and 42.2?(8)° with the benzoyl and aniline rings, respectively. In the crystal, the mol-ecules are linked into infinite chains by N-H?O hydrogen bonds.

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4-Chloro-N-(3,5-dimethyl-phen-yl)benzene-sulfonamide.

Project description:The asymmetric unit of the title compound, C(14)H(14)ClNO(2)S, contains two independent mol-ecules, which are twisted at the S atoms with C-SO(2)-NH-C torsion angles of -69.4?(7)° and 66.0?(8)°. The sulfonyl and the anilino benzene rings are tilted relative to each other by 49.0?(4) and 61.7?(3)° in the two mol-ecules. In the crystal, the mol-ecules are linked into chains by N-H?O hydrogen bonds.

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N-(2-Chloro-phen-yl)-2-(4,6-dimethyl-pyrimidin-2-ylsulfan-yl)acetamide.

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2-Chloro-N-(3,5-dichloro-phen-yl)acetamide.

Project description:The structure of the title compound, C(8)H(6)Cl(3)NO, is closely related to that of N-(3,5-dichloro-phen-yl)acetamide and other amides. The mol-ecular skeleton is essentially planar. The mol-ecules in the crystal structure are stabilized by N-H?O and N-H?Cl inter-molecular hydrogen bonds running along the a axis.

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N-(3-Chloro-phen-yl)acetamide.

Project description:The conformation of the N-H bond in the structure of the title compound (3CPA), C(8)H(8)ClNO, is anti to the meta-chloro substituent, in contrast to the syn conformation observed for the ortho-chloro substituent in N-(2-chloro-phen-yl)acetamide, syn to both the ortho and meta chloro substituents in N-(2,3-dichloro-phen-yl)acetamide, and syn to the ortho chloro substituent in N-(2,4-dichloro-phen-yl)acetamide. There are two mol-ecules, linked by an N-H?O hydrogen bond, in the asymmetric unit of 3CPA. The bond parameters in 3CPA are similar to those of other acetanilides and the mol-ecules are packed into chains through inter-molecular N-H?O hydrogen bonds.

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2-(4-Chloro-phen-yl)acetamide.

Project description:In the title compound, C(8)H(8)ClNO, the acetamide group is twisted out the benzene plane with a dihedral angle of 83.08 (1)°. In the crystal, mol-ecules are linked by N-H⋯O hydrogen bonds, forming layers parallel to the ab plane.

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