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2,2-Dichloro-N-(3,5-dimethyl-phen-yl)-acetamide.

ABSTRACT: The structure of the title compound, C(10)H(11)Cl(2)NO, resembles those of 2,2-dichloro-N-phenyl-acetamide, 2,2-dichloro-N-(2-methyl-phen-yl)acetamide, 2,2-dichloro-N-(3-methyl-phen-yl)-acetamide, 2,2-dichloro-N-(4-methyl-phen-yl)acetamide, N-(3,5-dimethyl-phen-yl)acetamide and other acetanilides, with similar bond parameters. The mol-ecules in the title compound are linked into infinite chains through N-H?O and C-H?O hydrogen bonding.

SUBMITTER: Gowda BT

PROVIDER: S-EPMC2915270 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

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2,2-Dichloro-N-(3,5-dimethyl-phen-yl)-acetamide.

Gowda B Thimme BT Svoboda Ingrid I Foro Sabine S Paulus Helmut H Fuess Hartmut H

Acta crystallographica. Section E, Structure reports online 20071206 Pt 1

The structure of the title compound, C(10)H(11)Cl(2)NO, resembles those of 2,2-dichloro-N-phenyl-acetamide, 2,2-dichloro-N-(2-methyl-phen-yl)acetamide, 2,2-dichloro-N-(3-methyl-phen-yl)-acetamide, 2,2-dichloro-N-(4-methyl-phen-yl)acetamide, N-(3,5-dimethyl-phen-yl)acetamide and other acetanilides, with similar bond parameters. The mol-ecules in the title compound are linked into infinite chains through N-H⋯O and C-H⋯O hydrogen bonding. ...[more]

PMID: 21200774

Similar Datasets

2,2-Dichloro-N-(3,4-dimethyl-phen-yl)acetamide.

Project description:In the title compound, C(10)H(11)Cl(2)NO, the N-H bond is syn to the 3-methyl substituent in the aromatic ring, similar to that observed in N-(3,4-dimethyl-phen-yl)acetamide and to the 3-chloro substituent in 2,2-dichloro-N-(3,4-dichloro-phen-yl)acetamide, and contrasting with the anti conformation observed for the 3-methyl substituent in 2,2,2-trichloro-N-(3,4-dimethyl-phen-yl)acetamide. On the other hand, it is anti to the C=O bond. An inter-molecular N-H?O hydrogen bond links mol-ecules into infinite chains along the b axis.

| S-EPMC2969347 | biostudies-literature

2,2-Dichloro-N-(2,3-dimethyl-phen-yl)acetamide.

Project description:The conformation of the N-H bond in the title compound, C(10)H(11)Cl(2)NO, is syn to both the 2- and 3-methyl substituents in the aromatic ring, similar to that of the 2-chloro and 3-chloro substituents in 2,2-dichloro-N-(2,3-dichloro-phen-yl)acetamide and the 2-methyl substituent in 2,2-dichloro-N-(2-methyl-phen-yl)acetamide, but in contrast to the anti conformation observed with respect to the 3-methyl substituent in 2,2-dichloro-N-(3-methyl-phen-yl)acetamide. The bond parameters in the title compound are similar to those in 2,2-dichloro-N-phenyl-acetamide and other acetanilides. The mol-ecules of the title compound are linked into chains through N-H⋯O and C-H⋯O hydrogen bonding.

| S-EPMC2915294 | biostudies-literature

2,2-Dichloro-N-(2,5-dichloro-phen-yl)acetamide.

Project description:The conformation of the N-H bond in the title compound, C(8)H(5)Cl(4)NO, is syn to the 2-chloro substituent and anti to the 5-chloro substituent in the aromatic ring. The bond parameters are similar to those in 2,2-dichloro-N-phenyl-acetamide and other acetanilides. In the crystal structure, the mol-ecules are linked into chains through N-H?O hydrogen bonding.

| S-EPMC2915043 | biostudies-literature

2-Chloro-N-(3,5-dichloro-phen-yl)acetamide.

Project description:The structure of the title compound, C(8)H(6)Cl(3)NO, is closely related to that of N-(3,5-dichloro-phen-yl)acetamide and other amides. The mol-ecular skeleton is essentially planar. The mol-ecules in the crystal structure are stabilized by N-H⋯O and N-H⋯Cl inter-molecular hydrogen bonds running along the a axis.

| S-EPMC2960189 | biostudies-literature

2,2-Dichloro-N-(3-nitro-phen-yl)acetamide.

Project description:The conformation of the N-H bond in the structure of the title compound (3NPDCA), C(8)H(6)Cl(2)N(2)O(3), is anti to the meta-nitro group, similar to that in the structures of 2-chloro-N-(3-nitro-phen-yl)acetamide (3NPCA) and 2,2,2-trichloro-N-(3-nitro-phen-yl)acetamide (3NPTCA), and the meta-chloro group in 2,2-dichloro-N-(3-chloro-phen-yl)acetamide (3CPDCA). The geometric parameters of 3NPDCA are similar to those of 2,2-dichloro-N-phenyl-acetamide, 3CPDCA, 3NPCA, 3NPTCA and other acetanilides. Inter-molecular N-H⋯O hydrogen bonds link the mol-ecules into chains running along the b axis.

| S-EPMC2960440 | biostudies-literature

2-Chloro-N-(3,5-dimethyl-phen-yl)acetamide.

Project description:The conformation of the C=O bond in the structure of the title compound, C(10)H(12)ClNO, is anti to the N-H bond and to the C-Cl bond in the side chain in all four independent mol-ecules comprising the asymmetric unit. In the crystal, inter-molecular N-H⋯O hydrogen bonds link the mol-ecules into supra-molecular chains.

| S-EPMC2977723 | biostudies-literature

N-{2-[2-(2,6-Dichloro-3,5-dimethoxy-phen-yl)ethen-yl]phen-yl}acetamide.

Project description:The C=C double bond in the title substituted stilbene, C(18)H(17)Cl(2)NO(3), has a trans arrangement of the aryl substit-uents. The aromatic ring of the 2-acetyl-amino-phenyl substit-uent is twisted by 39.9?(3)° with respect to the central C-C=C-C unit and that of the 2,6-dichloro-3,5-dimethoxy-phenyl substitutent is twisted by 42.7?(3)°.

| S-EPMC2968122 | biostudies-literature

N-(2,6-Dimethyl-phen-yl)-2,2-diphenyl-acetamide.

Project description:In the title compound, C(22)H(21)NO, the dihedral angle between the phenyl rings is 82.59?(7)°. The dimethyl-benzene ring forms dihedral angles of 52.86?(4) and 49.65?(5)° with the two phenyl rings. In the crystal, mol-ecules are linked by N-H?O hydrogen bonds, forming a C(4) chain along the c axis. The crystal also features C-H?? inter-actions.

| S-EPMC3344437 | biostudies-literature

N-(2,4-Dimethyl-phen-yl)-2,2-diphenyl-acetamide.

Project description:The asymmetric unit of the title compound, C(22)H(21)NO, consists of two crystallographically independent mol-ecules (A and B). Each mol-ecule contains two benzene rings and one dimethyl-benzene ring. The dihedral angle between the two benzene rings is 87.75 (16)° in mol-ecule A and 89.25 (16)° in mol-ecule B. In mol-ecule A, the dimethyl-benzene ring forms dihedral angles of 89.65 (8) and 42.98 (11)° with the two benzene rings, whereas the corresponding angles are equal to 63.15 (7) and 58.67 (10)° in mol-ecule B. An intra-molecular C-H⋯O hydrogen bond generates an S(6) ring motif in each mol-ecule. In the crystal, mol-ecules are linked by bifurcated (N,C)-H⋯O hydrogen bonds, generating R(2) (1)(6) ring motifs and forming infinite chains along the a axis. The crystal is further stabilized by C-H⋯π and π-π inter-actions with centroid-centroid distances of 3.8543 (18) and 3.930 (2) Å.

| S-EPMC3344457 | biostudies-literature

N-(3,5-Dichloro-phen-yl)-2,4-dimethyl-benzene-sulfonamide.

Project description:In the crystal structure of the title compound, C(14)H(13)Cl(2)NO(2)S, the conformation of the N-C bond in the C-SO(2)-NH-C segment has gauche torsions with respect to the S=O bonds. The mol-ecule is bent at the N atom, with an C-SO(2)-NH-C torsion angle of -54.9?(3)°. The two benzene rings are tilted relative to each other by 82.3?(2)°. The mol-ecules are linked into centrosymmetric R(2) (2)(8) motifs by N-H?O hydrogen bonds and C-H?? inter-actions along [100].

| S-EPMC2979206 | biostudies-literature

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