Ontology highlight
ABSTRACT:
SUBMITTER: Xie HS
PROVIDER: S-EPMC2977753 | biostudies-literature | 2009 Apr
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20090418 Pt 5
The title compound, C(23)H(18)BrN, was synthesized by the reaction of 4-bromo-benzaldehyde, naphthalen-2-amine and cyclo-hexa-none in tetra-hydro-furan, catalyzed by iodine. The saturated six-membered ring adopts a half-chair conformation, and the four vicinal rings form a helical conformation, which results in a significant deviation from planarity for the pyridine ring. In the crystal, a weak C-H⋯π inter-action occurs, leading to inversion dimers. ...[more]