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1-(2,4-Dinitro-phen-yl)-2-(1,2,3,4-tetra-hydro-naphthalen-1-yl-idene)hydrazine.

ABSTRACT: In the title compound, C(14)H(14)N(4)O(4), the dihedral angle between the benzene rings is 10.42?(8)°. The nitro groups make dihedral angles of 5.3?(2) and 6.47?(15)° with their parent ring and are oriented at 11.2?(3)° with respect to each other. An intra-molecular N-H?O hydrogen bond completes an S(6) ring motif. In the crystal, mol-ecules are linked by C-H?O inter-actions, thus forming (010) chains in which R(2) (2)(13) ring motifs are present. There also exist aromatic ?-? stacking inter-actions [centroid-centroid separation = 3.7046?(9)?Å].

SUBMITTER: Danish M

PROVIDER: S-EPMC3007257 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

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1-(2,4-Dinitro-phen-yl)-2-(1,2,3,4-tetra-hydro-naphthalen-1-yl-idene)hydrazine.

Danish M M Hamid Masood M Tahir M Nawaz MN Ahmad Nazir N Ghafoor Sabiha S

Acta crystallographica. Section E, Structure reports online 20100724 Pt 8

In the title compound, C(14)H(14)N(4)O(4), the dihedral angle between the benzene rings is 10.42 (8)°. The nitro groups make dihedral angles of 5.3 (2) and 6.47 (15)° with their parent ring and are oriented at 11.2 (3)° with respect to each other. An intra-molecular N-H⋯O hydrogen bond completes an S(6) ring motif. In the crystal, mol-ecules are linked by C-H⋯O inter-actions, thus forming (010) chains in which R(2) (2)(13) ring motifs are present. There also exist aromatic π-π stacking inter-act ...[more]

PMID: 21588393

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