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2-(4-Methoxy-phen-yl)-6-trifluoro-methyl-1H-pyrrolo[3,2-c]quinoline monohydrate.

ABSTRACT: In the title compound, C(19)H(13)F(3)N(2)O·H(2)O, the phenyl and pyrroloquinoline ring system are close to coplanar [dihedral angle = 10.94?(4)°]. The meth-oxy group also is almost coplanar with the phenyl ring [5.4?(1)°]. In the crystal structure N-H?O(water) and water-quinoline O-H?N hydrogen bonds build up a supra-molecular chain-like arrangement along [001]. The remaining H atom of the water mol-ecule does not take part in classical hydrogen bonds. Instead, this O-H bond points toward the center of the phenyl ring of a neighbouring mol-ecule. Weak C-H?O and C-H?? inter-actions are also present.

SUBMITTER: Dutkiewicz G

PROVIDER: S-EPMC2979020 | biostudies-literature | 2010 Apr

REPOSITORIES: biostudies-literature

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2-(4-Methoxy-phen-yl)-6-trifluoro-methyl-1H-pyrrolo[3,2-c]quinoline monohydrate.

Dutkiewicz Grzegorz G Mayekar Anil N AN Yathirajan H S HS Narayana B B Kubicki Maciej M

Acta crystallographica. Section E, Structure reports online 20100417 Pt 5

In the title compound, C(19)H(13)F(3)N(2)O·H(2)O, the phenyl and pyrroloquinoline ring system are close to coplanar [dihedral angle = 10.94 (4)°]. The meth-oxy group also is almost coplanar with the phenyl ring [5.4 (1)°]. In the crystal structure N-H⋯O(water) and water-quinoline O-H⋯N hydrogen bonds build up a supra-molecular chain-like arrangement along [001]. The remaining H atom of the water mol-ecule does not take part in classical hydrogen bonds. Instead, this O-H bond points toward the ce ...[more]

PMID: 21579163

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