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Bis(1,10-phenanthroline-?N,N')(sulfato-?O,O')zinc(II) propane-1,3-diol solvate.

ABSTRACT: In the title compound, [Zn(SO(4))(C(12)H(8)N(2))(2)]·C(3)H(8)O(2), the Zn(2+) ion (site symmetry 2) is coordinated by two chelating 1,10-phenanthroline ligands and an O,O'-bidentate sulfate ion (S site symmetry 2), resulting in a distorted cis-ZnO(2)N(4) octa-hedral geometry for the metal ion. The complete propane-1,3-diol mol-ecule is generated by crystallographic twofold symmetry and two O-H?O hydrogen bonds are formed with the uncoordinated O atoms of the sulfate group.

SUBMITTER: Cui JD 

PROVIDER: S-EPMC2979185 | biostudies-literature | 2010 Apr

REPOSITORIES: biostudies-literature

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Bis(1,10-phenanthroline-κN,N')(sulfato-κO,O')zinc(II) propane-1,3-diol solvate.

Cui Jiang-Dong JD   Zhong Kai-Long KL   Liu Yan-Yun YY  

Acta crystallographica. Section E, Structure reports online 20100424 Pt 5

In the title compound, [Zn(SO(4))(C(12)H(8)N(2))(2)]·C(3)H(8)O(2), the Zn(2+) ion (site symmetry 2) is coordinated by two chelating 1,10-phenanthroline ligands and an O,O'-bidentate sulfate ion (S site symmetry 2), resulting in a distorted cis-ZnO(2)N(4) octa-hedral geometry for the metal ion. The complete propane-1,3-diol mol-ecule is generated by crystallographic twofold symmetry and two O-H⋯O hydrogen bonds are formed with the uncoordinated O atoms of the sulfate group. ...[more]

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