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Bis(1,10-phenanthroline-?N,N')(sulfato-?O,O')nickel(II) ethane-1,2-diol solvate.

ABSTRACT: In the title compound, [Ni(SO(4))(C(12)H(8)N(2))(2)]·C(2)H(6)O(2), the coordination polyhedron around the Ni(2+) ion is a distorted octahedron, with four N atoms from two phenanthroline groups and two O atoms from a bidentate sulfate ligand. The Ni(2+) ion lies on a special position of site symmetry 2. Inter-molecular O-H?O hydrogen bonds help to stabilize the structure. The OH group of the ethane-1,2-diol solvent is disordered over two positions with equal occupancy.

SUBMITTER: Zhong KL

PROVIDER: S-EPMC2977342 | biostudies-literature | 2009 Jul

REPOSITORIES: biostudies-literature

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Bis(1,10-phenanthroline-κN,N')(sulfato-κO,O')nickel(II) ethane-1,2-diol solvate.

Zhong Kai-Long KL Ni Chao C Wang Jian-Mei JM

Acta crystallographica. Section E, Structure reports online 20090711 Pt 8

In the title compound, [Ni(SO(4))(C(12)H(8)N(2))(2)]·C(2)H(6)O(2), the coordination polyhedron around the Ni(2+) ion is a distorted octahedron, with four N atoms from two phenanthroline groups and two O atoms from a bidentate sulfate ligand. The Ni(2+) ion lies on a special position of site symmetry 2. Inter-molecular O-H⋯O hydrogen bonds help to stabilize the structure. The OH group of the ethane-1,2-diol solvent is disordered over two positions with equal occupancy. ...[more]

PMID: 21583369

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