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An ortho-rhom-bic polymorph of 1-benzyl-1H-benzimidazole.

ABSTRACT: The title compound, C(14)H(12)N(2), in contrast to the previously reported monoclinic polymorph [Lei et al. (2009 ?). Acta Cryst. E65, o2613], crystallizes in the ortho-rhom-bic crystal system. The dihedral angle between the imidazole ring system and the phenyl ring is 76.78?(16)°. Weak C-H?N and C-H?? inter-actions are observed in the crystal structure.

SUBMITTER: Zhang YJ

PROVIDER: S-EPMC2979212 | biostudies-literature | 2010 Apr

REPOSITORIES: biostudies-literature

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An ortho-rhom-bic polymorph of 1-benzyl-1H-benzimidazole.

Zhang Ying-Jun YJ Zhu Xue-Wen XW Qian Heng-Yu HY Yin Zhi-Gang ZG Zhang Chun-Xia CX

Acta crystallographica. Section E, Structure reports online 20100428 Pt 5

The title compound, C(14)H(12)N(2), in contrast to the previously reported monoclinic polymorph [Lei et al. (2009 ▶). Acta Cryst. E65, o2613], crystallizes in the ortho-rhom-bic crystal system. The dihedral angle between the imidazole ring system and the phenyl ring is 76.78 (16)°. Weak C-H⋯N and C-H⋯π inter-actions are observed in the crystal structure. ...[more]

PMID: 21579238

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