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An ortho-rhom-bic polymorph of cerium(III) ultraphosphate, CeP(5)O(14).

ABSTRACT: Cerium(III) ultraphosphate, CeP(5)O(14), was synthesized by a high-temperature solution reaction between CeO(2) and NH(4)H(2)PO(4) in a Ce-P molar ratio of 1:12. Colourless crystals of the ortho-rhom-bic polymorph were obtained by cooling the melt of the mixture. The structure contains (P(5)O(14))(3-) anionic ribbons linked by distorted CeO(8) polyhedra.

SUBMITTER: Zhu J 

PROVIDER: S-EPMC2959646 | biostudies-literature | 2008 Oct

REPOSITORIES: biostudies-literature

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An ortho-rhom-bic polymorph of cerium(III) ultraphosphate, CeP(5)O(14).

Zhu Jing J   Cheng Wen-Dan WD   Zhang Hao H  

Acta crystallographica. Section E, Structure reports online 20081015 Pt 11

Cerium(III) ultraphosphate, CeP(5)O(14), was synthesized by a high-temperature solution reaction between CeO(2) and NH(4)H(2)PO(4) in a Ce-P molar ratio of 1:12. Colourless crystals of the ortho-rhom-bic polymorph were obtained by cooling the melt of the mixture. The structure contains (P(5)O(14))(3-) anionic ribbons linked by distorted CeO(8) polyhedra. ...[more]

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