Ontology highlight
ABSTRACT:
SUBMITTER: Stibrany RT
PROVIDER: S-EPMC2979213 | biostudies-literature | 2010 Apr
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20100410 Pt 5
The title compound, [Co(C(10)H(10)BF(6)N(4))(C(15)H(13)BF(9)N(6))], is a neutral Co(II) complex which contains one each of the anionic ligands, bis-(3-trifluoro-methyl-5-methyl-pyrazol-1-yl)borate (Bp) and tris-(3-trifluoro-methyl-5-methyl-pyrazol-1-yl)borate (Tp). A distorted octa-hedral coordination geometry results from ligation of an H atom, which is part of an agostic B-H⋯Co inter-action (H⋯Co = 2.17 Å), and by five imine N atoms, two from a Bp ligand and three from a Tp ligand. In the crys ...[more]