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Tetra-aqua-bis(orotato-?O)cobalt(II) dihydrate.

ABSTRACT: In the title Co(II) complex, [Co(C(5)H(3)N(2)O(4))(2)(H(2)O)(4)]·2H(2)O, the Co(II) ion is located on an inversion center and is coordinated by two orotate (2,6-dioxo-1,2,3,6-tetrahydropyrimidine-4-carboxylate) anions and four water mol-ecules in a slightly distorted octa-hedral geometry. The dihedral angle between the carboxyl-ate group and the attached orotate ring is 1.2?(3)°. In the crystal structure, inter-molecular O-H?O, N-H?O and C-H?O hydrogen bonds link the mol-ecules into a three-dimensional network. ?-? contacts between the orotate rings [centroid-centroid distances = 3.439?(2) and 3.438?(2)?Å] further stabilize the structure.

SUBMITTER: Ay AN

PROVIDER: S-EPMC2979368 | biostudies-literature | 2010 May

REPOSITORIES: biostudies-literature

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Tetra-aqua-bis(orotato-κO)cobalt(II) dihydrate.

Ay Ahmet Nedim AN Köse Dursun Ali DA Tercan Barış B Yüksel Fatma F Hökelek Tuncer T

Acta crystallographica. Section E, Structure reports online 20100508 Pt 6

In the title Co(II) complex, [Co(C(5)H(3)N(2)O(4))(2)(H(2)O)(4)]·2H(2)O, the Co(II) ion is located on an inversion center and is coordinated by two orotate (2,6-dioxo-1,2,3,6-tetrahydropyrimidine-4-carboxylate) anions and four water mol-ecules in a slightly distorted octa-hedral geometry. The dihedral angle between the carboxyl-ate group and the attached orotate ring is 1.2 (3)°. In the crystal structure, inter-molecular O-H⋯O, N-H⋯O and C-H⋯O hydrogen bonds link the mol-ecules into a three-dime ...[more]

PMID: 21579272

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