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Tetra-aqua-bis-{3-carb-oxy-5-[(4-carb-oxy-phen-yl)diazen-yl]benzoato-?O}cobalt(II) dihydrate.

ABSTRACT: In the title complex, [Co(C(15)H(9)N(2)O(6))(2)(H(2)O)(4)]·2H(2)O, the Co(II) ion is located on an inversion center and is coordinated by two monodentate 3-carb-oxy-5-[(4-carb-oxy-phen-yl)diazen-yl]benzo-ate ligands and four water mol-ecules in a distorted octa-hedral geometry. In the crystal, inter-molecular O-H?O hydrogen bonds link the mol-ecules into a three-dimensional supra-molecular network.

SUBMITTER: Bai L

PROVIDER: S-EPMC3238615 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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Tetra-aqua-bis-{3-carb-oxy-5-[(4-carb-oxy-phen-yl)diazen-yl]benzoato-κO}cobalt(II) dihydrate.

Bai Liang L Zhao Jun J

Acta crystallographica. Section E, Structure reports online 20111105 Pt 12

In the title complex, [Co(C(15)H(9)N(2)O(6))(2)(H(2)O)(4)]·2H(2)O, the Co(II) ion is located on an inversion center and is coordinated by two monodentate 3-carb-oxy-5-[(4-carb-oxy-phen-yl)diazen-yl]benzo-ate ligands and four water mol-ecules in a distorted octa-hedral geometry. In the crystal, inter-molecular O-H⋯O hydrogen bonds link the mol-ecules into a three-dimensional supra-molecular network. ...[more]

PMID: 22199506

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catena-Poly[[[tetra-aqua-cobalt(II)]-?-4,4'-bipyridine-?N:N'] 2-[4-(2-carboxyl-ato-eth-yl)phen-oxy]acetate].

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