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5-Methyl-2,4-bis-(methyl-sulfan-yl)tricyclo-[6.2.1.0]undeca-4,9-diene-3,6-dione.

ABSTRACT: The structure analysis of the title compound, C(14)H(16)O(2)S(2), shows the SMe and H atoms of the bond linking the six-membered rings to be syn and also to be syn to the bridgehead -CH(2)- group. Each of the five-membered rings adopts an envelope conformation at the bridgehead -CH(2)- group. The dione-substituted ring adopts a folded conformation about the 1,4-C?C vector, with the ketone groups lying to one side. The cyclo-hexene ring adopts a boat conformation.

SUBMITTER: von Richthofen AA

PROVIDER: S-EPMC2979396 | biostudies-literature | 2010 May

REPOSITORIES: biostudies-literature

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5-Methyl-2,4-bis-(methyl-sulfan-yl)tricyclo-[6.2.1.0]undeca-4,9-diene-3,6-dione.

von Richthofen Andreas A AA Cardoso Filho José E P JE Marzorati Liliana L Zukerman-Schpector Julio J Tiekink Edward R T ER Di Vitta Claudio C

Acta crystallographica. Section E, Structure reports online 20100508 Pt 6

The structure analysis of the title compound, C(14)H(16)O(2)S(2), shows the SMe and H atoms of the bond linking the six-membered rings to be syn and also to be syn to the bridgehead -CH(2)- group. Each of the five-membered rings adopts an envelope conformation at the bridgehead -CH(2)- group. The dione-substituted ring adopts a folded conformation about the 1,4-C⋯C vector, with the ketone groups lying to one side. The cyclo-hexene ring adopts a boat conformation. ...[more]

PMID: 21579362

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