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(5''E)-1''-Benzyl-1'-methyl-5''-[4-(methyl-sulfan-yl)benzyl-idene]-4'-[4-(methyl-sulfan-yl)phen-yl]dispiro-[indoline-3,2'-pyrrolidine-3',3''-piperidine]-2,4''-dione dichloro-methane solvate.

ABSTRACT: In the title compound, C(38)H(36)N(3)O(2)S(2)·CH(2)Cl(2), the 2-oxindole ring is almost planar (r.m.s. deviation = 0.032?Å), the pyrrolidine ring adopts a twist conformation and the piperidone ring exists as a chair. Three short C-H?O intra-molecular contacts occur. In the crystal, mol-ecules are linked by C-H?O and C-H?N inter-actions. The dichloro-methane solvent mol-ecule is disordered over two orientations in a 0.765?(11):0.235?(11) ratio.

SUBMITTER: Hou Y

PROVIDER: S-EPMC2980017 | biostudies-literature | 2009 Dec

REPOSITORIES: biostudies-literature

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(5''E)-1''-Benzyl-1'-methyl-5''-[4-(methyl-sulfan-yl)benzyl-idene]-4'-[4-(methyl-sulfan-yl)phen-yl]dispiro-[indoline-3,2'-pyrrolidine-3',3''-piperidine]-2,4''-dione dichloro-methane solvate.

Hou Yongjiang Y

Acta crystallographica. Section E, Structure reports online 20091224 Pt 1

In the title compound, C(38)H(36)N(3)O(2)S(2)·CH(2)Cl(2), the 2-oxindole ring is almost planar (r.m.s. deviation = 0.032 Å), the pyrrolidine ring adopts a twist conformation and the piperidone ring exists as a chair. Three short C-H⋯O intra-molecular contacts occur. In the crystal, mol-ecules are linked by C-H⋯O and C-H⋯N inter-actions. The dichloro-methane solvent mol-ecule is disordered over two orientations in a 0.765 (11):0.235 (11) ratio. ...[more]

PMID: 21580125

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