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4-Methyl-benzene-carbothio-amide.

ABSTRACT: In the title mol-ecule, C(8)H(9)NS, the mean plane of the carbothio-amide group is twisted slightly with respect to the mean plane of the benzene ring, making a dihedral angle of 17.03?(10)°. The crystal structure is stabilized by inter-molecular N-H?S hydrogen bonds, resulting in the formation of eight-membered rings lying about inversion centers and representing R(2) (2)(8) and R(4) (2)(8) motifs. Futhermore, these hydrogen bonds build up chains parallel to the b axis.

SUBMITTER: Ali S

PROVIDER: S-EPMC2979520 | biostudies-literature | 2010 May

REPOSITORIES: biostudies-literature

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4-Methyl-benzene-carbothio-amide.

Ali Saqib S Hameed Shahid S Luqman Ahmad A Akhtar Tashfeen T Parvez Masood M

Acta crystallographica. Section E, Structure reports online 20100508 Pt 6

In the title mol-ecule, C(8)H(9)NS, the mean plane of the carbothio-amide group is twisted slightly with respect to the mean plane of the benzene ring, making a dihedral angle of 17.03 (10)°. The crystal structure is stabilized by inter-molecular N-H⋯S hydrogen bonds, resulting in the formation of eight-membered rings lying about inversion centers and representing R(2) (2)(8) and R(4) (2)(8) motifs. Futhermore, these hydrogen bonds build up chains parallel to the b axis. ...[more]

PMID: 21579372

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