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1-De-oxy-1-fluoro-l-galactitol.

ABSTRACT: The crystal structure unequivocally confirms the relative stereochemistry of the title compound, C(6)H(13)FO(5) [6-de-oxy-6-fluoro-d-galactitol or (2S,3R,4R,5S)-6-fluoro-hexane-1,2,3,4,5-penta-ol]. The absolute stereochemistry was determined from the use of d-galactose as the starting material. In the crystal, the molecules are linked by O-H?O and O-H?F hydrogen bonds, forming a three-dimensional network with each mol-ecule acting as a donor and acceptor for five hydrogen bonds.

SUBMITTER: Jenkinson SF 

PROVIDER: S-EPMC2979521 | biostudies-literature | 2010 May

REPOSITORIES: biostudies-literature

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1-De-oxy-1-fluoro-l-galactitol.

Jenkinson Sarah F SF   Best Daniel D   Izumori Ken K   Wilson Francis X FX   Weymouth-Wilson Alexander C AC   Fleet George W J GW   Thompson Amber L AL  

Acta crystallographica. Section E, Structure reports online 20100512 Pt 6

The crystal structure unequivocally confirms the relative stereochemistry of the title compound, C(6)H(13)FO(5) [6-de-oxy-6-fluoro-d-galactitol or (2S,3R,4R,5S)-6-fluoro-hexane-1,2,3,4,5-penta-ol]. The absolute stereochemistry was determined from the use of d-galactose as the starting material. In the crystal, the molecules are linked by O-H⋯O and O-H⋯F hydrogen bonds, forming a three-dimensional network with each mol-ecule acting as a donor and acceptor for five hydrogen bonds. ...[more]

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