Unknown

Dataset Information

0

1-De-oxy-1-fluoro-l-galactitol.

ABSTRACT: The crystal structure unequivocally confirms the relative stereochemistry of the title compound, C(6)H(13)FO(5) [6-de-oxy-6-fluoro-d-galactitol or (2S,3R,4R,5S)-6-fluoro-hexane-1,2,3,4,5-penta-ol]. The absolute stereochemistry was determined from the use of d-galactose as the starting material. In the crystal, the molecules are linked by O-H?O and O-H?F hydrogen bonds, forming a three-dimensional network with each mol-ecule acting as a donor and acceptor for five hydrogen bonds.

SUBMITTER: Jenkinson SF 

PROVIDER: S-EPMC2979521 | biostudies-literature | 2010 May

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

1-De-oxy-1-fluoro-l-galactitol.

Jenkinson Sarah F SF   Best Daniel D   Izumori Ken K   Wilson Francis X FX   Weymouth-Wilson Alexander C AC   Fleet George W J GW   Thompson Amber L AL  

Acta crystallographica. Section E, Structure reports online 20100512 Pt 6

The crystal structure unequivocally confirms the relative stereochemistry of the title compound, C(6)H(13)FO(5) [6-de-oxy-6-fluoro-d-galactitol or (2S,3R,4R,5S)-6-fluoro-hexane-1,2,3,4,5-penta-ol]. The absolute stereochemistry was determined from the use of d-galactose as the starting material. In the crystal, the molecules are linked by O-H⋯O and O-H⋯F hydrogen bonds, forming a three-dimensional network with each mol-ecule acting as a donor and acceptor for five hydrogen bonds. ...[more]

Similar Datasets

Unknown 1-De-oxy-d-galactitol (l-fucitol).
| S-EPMC2962223 | biostudies-literature
Unknown 6-De-oxy-6-fluoro-d-galactose.
| S-EPMC2979621 | biostudies-literature
Unknown 1-(2-Fluoro-benz-yl)-1-(2-fluoro-benz-yl-oxy)urea.
| S-EPMC2968304 | biostudies-literature
Unknown 4-(4-Fluoro-phen-oxy)benzoic acid.
| S-EPMC2977365 | biostudies-literature
Unknown 1,3-Bis(2,3,5,6-tetra-fluoro-4-iodo-phen-oxy)-2,2-bis-[(2,3,5,6-tetra-fluoro-4-iodo-phen-oxy)meth-yl]propane.
| S-EPMC3629626 | biostudies-literature
Unknown 4-Meth-oxy-anilinium hexa-fluoro-phosphate monohydrate.
| S-EPMC3006782 | biostudies-literature
Unknown 1-De-oxy-d-arabinitol.
| S-EPMC2961547 | biostudies-literature
Unknown 1-De-oxy-l-mannitol (6-de-oxy-l-mannitol or l-rhamnitol).
| S-EPMC2960544 | biostudies-other
Unknown 2-Fluoro-4-(meth-oxy-carbon-yl)benzoic acid.
| S-EPMC3008027 | biostudies-literature
Unknown 2-Fluoro-N'-(2-meth-oxy-benzyl-idene)benzohydrazide.
| S-EPMC3050391 | biostudies-literature