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Spiro-[1,3-dioxolane-2,3'-indolin]-2'-one.

ABSTRACT: The title compound, C(10)H(9)NO(3), was synthesized by the condensation reaction of isatin (systematic name 1H-indole-2,3-dione) with glycol in presence of p-toluene-sulfonic acid. The indol-2-one ring system is essentially planar [N-C-C-C torsion angle = 3.1?(2)°], and the 1,3-dioxolane ring is slightly distorted. The crystal structure exhibits inter-molecular N-H?O hydrogen bonds.

SUBMITTER: Meng Y

PROVIDER: S-EPMC2979575 | biostudies-literature | 2010 May

REPOSITORIES: biostudies-literature

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Spiro-[1,3-dioxolane-2,3'-indolin]-2'-one.

Meng Yan Y Miao Yanqing Y

Acta crystallographica. Section E, Structure reports online 20100512 Pt 6

The title compound, C(10)H(9)NO(3), was synthesized by the condensation reaction of isatin (systematic name 1H-indole-2,3-dione) with glycol in presence of p-toluene-sulfonic acid. The indol-2-one ring system is essentially planar [N-C-C-C torsion angle = 3.1 (2)°], and the 1,3-dioxolane ring is slightly distorted. The crystal structure exhibits inter-molecular N-H⋯O hydrogen bonds. ...[more]

PMID: 21579401

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