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1-(1-Carboxy-methyl-1,4-anhydro-2,3-O-isopropyl-idene-?-d-erythrofuranos-yl)thymine.

ABSTRACT: X-Ray crystallography unequivocally determined the stereochemistry of the thymine base in the title compound, C(14)H(18)N(2)O(7). The absolute stereochemistry was determined from the use of d-ribose as the starting material. There are two independent mol-ecules in the asymmetric unit (Z' = 2) which exist as N-H?O hydrogen-bonded pairs in the crystal structure.

SUBMITTER: Lenagh-Snow GM

PROVIDER: S-EPMC2979716 | biostudies-literature | 2010 Jan

REPOSITORIES: biostudies-literature

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1-(1-Carboxy-methyl-1,4-anhydro-2,3-O-isopropyl-idene-α-d-erythrofuranos-yl)thymine.

Lenagh-Snow G M J GM Jenkinson S F SF Stewart A J AJ Fleet G W J GW Watkin D J DJ

Acta crystallographica. Section E, Structure reports online 20100120 Pt 2

X-Ray crystallography unequivocally determined the stereochemistry of the thymine base in the title compound, C(14)H(18)N(2)O(7). The absolute stereochemistry was determined from the use of d-ribose as the starting material. There are two independent mol-ecules in the asymmetric unit (Z' = 2) which exist as N-H⋯O hydrogen-bonded pairs in the crystal structure. ...[more]

PMID: 21579824

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