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(Bis{2-[3-(2,4,6-trimethyl-benz-yl)imid-azolin-2-yliden-1-yl-?C]-4-methyl-phenyl}amido-?N)chloridopalladium(II).

ABSTRACT: The coordination geometry about the Pd centre in the title compound, [Pd(C(40)H(42)N(5))Cl], is approximately square-planar. The CNC pincer-type N-heterocyclic carbene ligand binds to the Pd atom in a tridentate fashion by the amido N atom and the two carbene atoms and generates two six-membered chelate rings, completing the coordination.

SUBMITTER: Cheng GJ

PROVIDER: S-EPMC2979753 | biostudies-literature | 2010 Jan

REPOSITORIES: biostudies-literature

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(Bis{2-[3-(2,4,6-trimethyl-benz-yl)imid-azolin-2-yliden-1-yl-κC]-4-methyl-phenyl}amido-κN)chloridopalladium(II).

Cheng Guan-Jun GJ Wei Wei W Zhou Chuang C Luo Mei-Ming MM

Acta crystallographica. Section E, Structure reports online 20100123 Pt 2

The coordination geometry about the Pd centre in the title compound, [Pd(C(40)H(42)N(5))Cl], is approximately square-planar. The CNC pincer-type N-heterocyclic carbene ligand binds to the Pd atom in a tridentate fashion by the amido N atom and the two carbene atoms and generates two six-membered chelate rings, completing the coordination. ...[more]

PMID: 21579662

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