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Dibromidodi-?-hydroxido-di-?(3)-oxido-octa-phenyl-tetra-tin(IV).

ABSTRACT: In the centrosymmetric title compound, [Sn(4)Br(2)(C(6)H(5))(8)O(2)(OH)(2)], the four tin(IV) atoms are bridged by the hydroxo and oxo ligands, forming a ladder-like array of three edge-connected Sn(2)O(2) squares. The two independent tin atoms show distorted trigonal-bipyramidal SnC(2)O(3) and SnC(2)O(2)Br coordination geometries.

SUBMITTER: Yap QL

PROVIDER: S-EPMC2980054 | biostudies-literature | 2009 Dec

REPOSITORIES: biostudies-literature

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Dibromidodi-μ-hydroxido-di-μ(3)-oxido-octa-phenyl-tetra-tin(IV).

Yap Quai Ling QL Lo Kong Mun KM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20091204 Pt 1

In the centrosymmetric title compound, [Sn(4)Br(2)(C(6)H(5))(8)O(2)(OH)(2)], the four tin(IV) atoms are bridged by the hydroxo and oxo ligands, forming a ladder-like array of three edge-connected Sn(2)O(2) squares. The two independent tin atoms show distorted trigonal-bipyramidal SnC(2)O(3) and SnC(2)O(2)Br coordination geometries. ...[more]

PMID: 21579973

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Crystal structures of di-aquadi-?-hydroxido-tris-[tri-methyl-tin(IV)] diformatotri-methyl-stannate(IV) and di-?-hydroxido-tris-[tri-methyl-tin(IV)] chloride monohydrate.

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