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Dichloridodi-?(2)-hydroxido-di-?(3)-oxido-octa-phenyl-tetra-tin(IV) dimethyl sulfoxide disolvate.

ABSTRACT: In the centrosymmetric tetra-nuclear title mol-ecule, [Sn(4)(C(6)H(5))(8)Cl(2)O(2)(OH)(2)]·2C(2)H(6)OS, the two independent tin(IV) atoms show distorted trigonal-bipyramidal SnC(2)O(3) and SnC(2)O(2)Cl coordination geometries. The four tin(IV) atoms are bridged by the hydroxo and oxo ligands, forming a ladder-like array of three edge-connected Sn(2)O(2) squares. The solvent mol-ecules are linked to the tetra-nuclear mol-ecule via O-H?O hydrogen bonds.

SUBMITTER: Foladi S

PROVIDER: S-EPMC3569190 | biostudies-literature | 2013 Feb

REPOSITORIES: biostudies-literature

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Dichloridodi-μ(2)-hydroxido-di-μ(3)-oxido-octa-phenyl-tetra-tin(IV) dimethyl sulfoxide disolvate.

Foladi Shahrbano S Khazaei Parivash P Attar Gharamaleki Jafar J Notash Behrouz B Rofouei Mohammad Kazem MK

Acta crystallographica. Section E, Structure reports online 20130109 Pt 2

In the centrosymmetric tetra-nuclear title mol-ecule, [Sn(4)(C(6)H(5))(8)Cl(2)O(2)(OH)(2)]·2C(2)H(6)OS, the two independent tin(IV) atoms show distorted trigonal-bipyramidal SnC(2)O(3) and SnC(2)O(2)Cl coordination geometries. The four tin(IV) atoms are bridged by the hydroxo and oxo ligands, forming a ladder-like array of three edge-connected Sn(2)O(2) squares. The solvent mol-ecules are linked to the tetra-nuclear mol-ecule via O-H⋯O hydrogen bonds. ...[more]

PMID: 23424434

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