Unknown

Dataset Information

0

Poly[diaqua-bis(?-4-carb-oxy-2-propyl-1H-imidazole-5-carboxyl-ato-?N,O:O)calcium(II)].

ABSTRACT: In the title complex, [Ca(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)](n), the Ca(II) atom is eight-coordinated in a distorted square-anti-prismatic environment. The water-coordinated Ca atom is N,O-chelated by the monocarboxyl-ate anion; the carboxyl -CO(2) portion engaged in chelation bears an acid hydrogen. The free -CO(2) portion engages in bonding to adjacent Ca atoms. The Ca(II) centres are connected through the ligand, forming a layer structure; the layers are linked by hydrogen bonds into a three-dimensional network.

SUBMITTER: Song WD 

PROVIDER: S-EPMC2980060 | biostudies-literature | 2009 Dec

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Poly[diaqua-bis(μ-4-carb-oxy-2-propyl-1H-imidazole-5-carboxyl-ato-κN,O:O)calcium(II)].

Song Wen-Dong WD   Yan Jian-Bin JB   Li Shi-Jie SJ   Miao Dong-Liang DL   Li Xiao-Fei XF  

Acta crystallographica. Section E, Structure reports online 20091212 Pt 1

In the title complex, [Ca(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)](n), the Ca(II) atom is eight-coordinated in a distorted square-anti-prismatic environment. The water-coordinated Ca atom is N,O-chelated by the monocarboxyl-ate anion; the carboxyl -CO(2) portion engaged in chelation bears an acid hydrogen. The free -CO(2) portion engages in bonding to adjacent Ca atoms. The Ca(II) centres are connected through the ligand, forming a layer structure; the layers are linked by hydrogen bonds into a three-dim  ...[more]

Similar Datasets

Unknown Poly[diaqua-bis(μ(2)-5-carb-oxy-2-propyl-1H-imidazole-4-carboxyl-ato-κN,O:O)lead(II)].
| S-EPMC2979092 | biostudies-literature
Unknown Diaqua-bis-(5-carb-oxy-2-propyl-1H-imidazole-4-carboxyl-ato-?N,O)cobalt(II) 3.5-hydrate.
| S-EPMC3050148 | biostudies-literature
Unknown Diaqua-bis-(5-carb-oxy-2-propyl-1H-imidazole-4-carboxyl-ato-?N,O)nickel(II) tetra-hydrate.
| S-EPMC3007488 | biostudies-literature
Unknown Diaqua-bis(5-carb-oxy-2-propyl-1H-imidazole-4-carboxyl-ato-?N,O)magnesium(II) 3.5-hydrate.
| S-EPMC2983537 | biostudies-literature
Unknown Diaqua-bis-(5-carb-oxy-2-propyl-1H-imidazole-4-carboxyl-ato-?N,O)zinc(II) 3.5-hydrate.
| S-EPMC3008058 | biostudies-literature
Unknown Diaqua-bis-(5-carb-oxy-1H-imidazole-4-carboxyl-ato-?N,O)iron(II).
| S-EPMC3151786 | biostudies-literature
Unknown Diaqua-bis-(5-carb-oxy-2-propyl-1H-imidazole-4-carboxyl-ato-?N,O)cadmium N,N-dimethyl-formamide disolvate.
| S-EPMC3238758 | biostudies-literature
Unknown Diaqua-bis(5-carb-oxy-2-propyl-1H-imidazole-4-carboxyl-ato-?N,O)manganese(II) N,N-dimethyl-formamide disolvate.
| S-EPMC2980198 | biostudies-literature
Unknown Diaqua-bis-(4-carb-oxy-2-propyl-1H-imidazole-5-carboxyl-ato-?N,O)cobalt(II) N,N-dimethyl-formamide disolvate.
| S-EPMC3009030 | biostudies-literature
Unknown Diaqua-bis-(4-carb-oxy-2-propyl-1H-imidazole-5-carboxyl-ato-?N,O)copper(II) N,N-dimethyl-formamide disolvate.
| S-EPMC3007369 | biostudies-literature