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4-Chloro-N-(2-methoxy-phen-yl)benzamide.

ABSTRACT: The title compound, C(14)H(12)ClNO(2), was prepared by refluxing 4-chloro-benzoyl chloride with o-anisidine in CHCl(3). The methoxy-phen-yl-amide segment of the mol-ecule is almost planar, with a dihedral angle of 5.10?(7)° between the benzene ring and the C-N-C(O)-C fragment. A weak intra-molecular N-H?O contact forms an S(5) ring and contributes to the planarity of this portion of the mol-ecule. The two benzene rings are inclined at an angle of 26.74?(7)°. In the crystal structure, inter-molecular Cl?O inter-actions of 3.1874?(9)?Å generate centrosymmetric dimers. These are further linked by C-H?O and C-H?? inter-actions, forming inversion related sheets parallel to [001].

SUBMITTER: Saeed A

PROVIDER: S-EPMC2980066 | biostudies-literature | 2009 Dec

REPOSITORIES: biostudies-literature

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4-Chloro-N-(2-methoxy-phen-yl)benzamide.

Saeed Aamer A Khera Rasheed Ahmad RA Simpson Jim J

Acta crystallographica. Section E, Structure reports online 20091219 Pt 1

The title compound, C(14)H(12)ClNO(2), was prepared by refluxing 4-chloro-benzoyl chloride with o-anisidine in CHCl(3). The methoxy-phen-yl-amide segment of the mol-ecule is almost planar, with a dihedral angle of 5.10 (7)° between the benzene ring and the C-N-C(O)-C fragment. A weak intra-molecular N-H⋯O contact forms an S(5) ring and contributes to the planarity of this portion of the mol-ecule. The two benzene rings are inclined at an angle of 26.74 (7)°. In the crystal structure, inter-molec ...[more]

PMID: 21580098

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