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N-(4-Chloro-phen-yl)-2-methyl-benzamide.

ABSTRACT: In the structure of the title compound, C(14)H(12)ClNO, the N-H and C=O bonds are trans to each other. Furthermore, the C=O bond is syn to the ortho-methyl group in the benzoyl ring, similar to what is observed in 2-methyl-N-(4-methyl-phen-yl)benzamide and 2-methyl-N-phenyl-benzamide. The amide linkage (-NHCO-) makes dihedral angles of 36.9?(7) and 46.4?(5)° with the aniline and benzoyl rings, respectively, while the dihedral angle between the benzoyl and aniline rings is 83.1?(1)°. In the crystal structure, mol-ecules form chains running along the b axis through N-H?O hydrogen bonds.

SUBMITTER: Gowda BT 

PROVIDER: S-EPMC2968167 | biostudies-literature | 2009 Jan

REPOSITORIES: biostudies-literature

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N-(4-Chloro-phen-yl)-2-methyl-benzamide.

Gowda B Thimme BT   Foro Sabine S   Sowmya B P BP   Terao Hiromitsu H   Fuess Hartmut H  

Acta crystallographica. Section E, Structure reports online 20090128 Pt 2

In the structure of the title compound, C(14)H(12)ClNO, the N-H and C=O bonds are trans to each other. Furthermore, the C=O bond is syn to the ortho-methyl group in the benzoyl ring, similar to what is observed in 2-methyl-N-(4-methyl-phen-yl)benzamide and 2-methyl-N-phenyl-benzamide. The amide linkage (-NHCO-) makes dihedral angles of 36.9 (7) and 46.4 (5)° with the aniline and benzoyl rings, respectively, while the dihedral angle between the benzoyl and aniline rings is 83.1 (1)°. In the cryst  ...[more]

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