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Catena-Poly[[dianilinedichloridocopper(II)]-?(2)-2,5-bis-(4-pyrid-yl)-1,3,4-oxadiazole].

ABSTRACT: In the title compound, [CuCl(2)(C(6)H(7)N)(2)(C(12)H(8)N(4)O)](n), the Cu atom, located on an inversion center, is coordinated by four N atoms from two aniline ligands and two 2,5-bis-(4-pyrid-yl)-1,3,4-oxadiazole ligands. Two Cl atoms lying above and below the plane formed by these four N atoms inter-act weakly with the Cu atom [Cu-Cl = 2.7870?(7)?Å]. The trans 2,5-bis-(4-pyrid-yl)-1,3,4-oxadiazole ligands act as bridging ligands, linking adjacent Cu atoms and forming a one-dimensional coordination polymer. Two anilines coordinate with each Cu atom as terminal groups. The structure contains two classical N-H?Cl and two non-classical C-H?Cl hydrogen bonds.

SUBMITTER: Meng Q

PROVIDER: S-EPMC2980127 | biostudies-literature | 2009 Dec

REPOSITORIES: biostudies-literature

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catena-Poly[[dianilinedichloridocopper(II)]-μ(2)-2,5-bis-(4-pyrid-yl)-1,3,4-oxadiazole].

Meng Qinglong Q Wu Yiming Y Zhang Chi C

Acta crystallographica. Section E, Structure reports online 20091224 Pt 1

In the title compound, [CuCl(2)(C(6)H(7)N)(2)(C(12)H(8)N(4)O)](n), the Cu atom, located on an inversion center, is coordinated by four N atoms from two aniline ligands and two 2,5-bis-(4-pyrid-yl)-1,3,4-oxadiazole ligands. Two Cl atoms lying above and below the plane formed by these four N atoms inter-act weakly with the Cu atom [Cu-Cl = 2.7870 (7) Å]. The trans 2,5-bis-(4-pyrid-yl)-1,3,4-oxadiazole ligands act as bridging ligands, linking adjacent Cu atoms and forming a one-dimensional coordina ...[more]

PMID: 21579986

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