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Poly[bis-[?(2)-1,4-bis-(1,2,4-triazol-1-yl-meth-yl)benzene-?N:N]bis(nitrito-?O)cobalt(II)].

ABSTRACT: The Co(II) atom in the title complex, [Co(NO(2))(2)(C(12)H(12)N(6))(2)](n), lies on an inversion center and is coordinated by four N atoms from the triazole rings of two symmetry-related pairs of 1,4-bis-(1,2,4-triazol-1-ylmeth-yl)benzene (bbtz) ligands and two O atoms from two symmetry-related monodentate nitrate ligands in a distorted octa-hedral geometry. The Co atoms are bridged by four bbtz ligands, forming a two-dimensional (4,4) network parallel to (102).

SUBMITTER: Zhu X 

PROVIDER: S-EPMC2980217 | biostudies-literature | 2009 Dec

REPOSITORIES: biostudies-literature

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Poly[bis-[μ(2)-1,4-bis-(1,2,4-triazol-1-yl-meth-yl)benzene-κN:N]bis(nitrito-κO)cobalt(II)].

Zhu Xia X   Guo Ying Y   Zou Yun-Ling YL  

Acta crystallographica. Section E, Structure reports online 20091219 Pt 1

The Co(II) atom in the title complex, [Co(NO(2))(2)(C(12)H(12)N(6))(2)](n), lies on an inversion center and is coordinated by four N atoms from the triazole rings of two symmetry-related pairs of 1,4-bis-(1,2,4-triazol-1-ylmeth-yl)benzene (bbtz) ligands and two O atoms from two symmetry-related monodentate nitrate ligands in a distorted octa-hedral geometry. The Co atoms are bridged by four bbtz ligands, forming a two-dimensional (4,4) network parallel to (102). ...[more]

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