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Catena-Poly[[bis-(nitrato-?O)cobalt(II)]-bis-[?-1,4-bis-(pyridin-3-ylmeth-oxy)benzene-?N:N']].


ABSTRACT: In the title compound, [Co(NO(3))(2)(C(18)H(16)N(2)O(2))(2)](n), the Co(II) ion is located on an inversion center and is six-coordinated in an octa-hedral environment defined by four N atoms of the pyridine rings and two O atoms of the nitrate anions. The ligands link the Co(II) ions into a linear chain running along [201]. One O atom of the nitrate ligand is disordered over two positions with site-occupancy factors of 0.59?(4) and 0.41?(4).

SUBMITTER: Liu Y 

PROVIDER: S-EPMC3120598 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

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catena-Poly[[bis-(nitrato-κO)cobalt(II)]-bis-[μ-1,4-bis-(pyridin-3-ylmeth-oxy)benzene-κN:N']].

Liu Ying Y   Zhang Hong-Sen HS   Hou Guang-Feng GF   Gao Jin-Sheng JS  

Acta crystallographica. Section E, Structure reports online 20110525 Pt 6


In the title compound, [Co(NO(3))(2)(C(18)H(16)N(2)O(2))(2)](n), the Co(II) ion is located on an inversion center and is six-coordinated in an octa-hedral environment defined by four N atoms of the pyridine rings and two O atoms of the nitrate anions. The ligands link the Co(II) ions into a linear chain running along [201]. One O atom of the nitrate ligand is disordered over two positions with site-occupancy factors of 0.59 (4) and 0.41 (4). ...[more]

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