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(4'-All-yloxy-2,2':6',2''-terpyridine-?N,N',N'')(dibenzoyl-methanido-?O,O')bis-(nitrato-?O,O')neodymium(III) acetonitrile solvate.

ABSTRACT: The title complex, [Nd(C(15)H(11)O(2))(NO(3))(2)(C(18)H(15)N(3)O)]·CH(3)CN or [Nd(altpy)(dbm)(NO(3))(2)]·CH(3)CN (altpy = 4'-all-yl-oxy-2,2':6',2''-terpyridine, dbm = dibenzoyl-methanide anion), has been synthesized from 4'-all-yloxy-2,2':6',2''-terpyridine, dibenzoyl-methanate and neodymium nitrate. The Nd(3+) atom is nine-coordinated by two O atoms from the bidentate dbm ligand, three N atoms from the tridentate altpy ligand and four O atoms from two nitrate anions that act as bidentate ligands and occupy mutually trans sites in a distorted monocapped square-anti-prismatic geometry.

SUBMITTER: Mei Q

PROVIDER: S-EPMC2980225 | biostudies-literature | 2009 Dec

REPOSITORIES: biostudies-literature

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(4'-All-yloxy-2,2':6',2''-terpyridine-κN,N',N'')(dibenzoyl-methanido-κO,O')bis-(nitrato-κO,O')neodymium(III) acetonitrile solvate.

Mei Qunbo Q Tong Bihai B

Acta crystallographica. Section E, Structure reports online 20091204 Pt 1

The title complex, [Nd(C(15)H(11)O(2))(NO(3))(2)(C(18)H(15)N(3)O)]·CH(3)CN or [Nd(altpy)(dbm)(NO(3))(2)]·CH(3)CN (altpy = 4'-all-yl-oxy-2,2':6',2''-terpyridine, dbm = dibenzoyl-methanide anion), has been synthesized from 4'-all-yloxy-2,2':6',2''-terpyridine, dibenzoyl-methanate and neodymium nitrate. The Nd(3+) atom is nine-coordinated by two O atoms from the bidentate dbm ligand, three N atoms from the tridentate altpy ligand and four O atoms from two nitrate anions that act as bidentate ligand ...[more]

PMID: 21579918

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