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Dichloridobis[2-(2-fur-yl)-1-(2-furylmeth-yl)-1H-benzimidazole-?N]cadmium(II).


ABSTRACT: In the title complex, [CdCl(2)(C(16)H(12)N(2)O(2))(2)], the Cd(II) ion exhibits site symmetry 2. It shows a distorted tetra-hedral coordination defined by two N atoms from symmetry-related 2-(2-fur-yl)-1-(2-furylmeth-yl)-1H-benzimidazole ligands and by two symmetry-related Cl atoms. Intra-molecular C-H?O hydrogen bonds stabilize the mol-ecular configuration. Adjacent mol-ecules are linked through C-H?Cl hydrogen bonds into a network structure.

SUBMITTER: Wang X 

PROVIDER: S-EPMC2983315 | biostudies-literature | 2010 Sep

REPOSITORIES: biostudies-literature

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Dichloridobis[2-(2-fur-yl)-1-(2-furylmeth-yl)-1H-benzimidazole-κN]cadmium(II).

Wang Xia X   Li Yu-Xian YX   Liu Yan-Ju YJ   Yang Huai-Xia HX   Zhang Cong-Cong CC  

Acta crystallographica. Section E, Structure reports online 20100904 Pt 10


In the title complex, [CdCl(2)(C(16)H(12)N(2)O(2))(2)], the Cd(II) ion exhibits site symmetry 2. It shows a distorted tetra-hedral coordination defined by two N atoms from symmetry-related 2-(2-fur-yl)-1-(2-furylmeth-yl)-1H-benzimidazole ligands and by two symmetry-related Cl atoms. Intra-molecular C-H⋯O hydrogen bonds stabilize the mol-ecular configuration. Adjacent mol-ecules are linked through C-H⋯Cl hydrogen bonds into a network structure. ...[more]

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