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[Benz-yl(2-pyridyl-methyl-idene)amine]-dichloridomercury(II).

ABSTRACT: The Hg(II) ion in the title complex, [HgCl(2)(C(13)H(12)N(2))], adopts a distorted tetra-hedral geometry being coordinated by two Cl anions and by two N atoms of the benz-yl(2-pyridyl-methyl-ene)amine ligand. The Cl-Hg-Cl plane is twisted at 70.1?(1)° from the mean plane of the chelate ring. In the crystal structure, inter-molecular ?-? inter-actions [centroid-centroid distance = 3.793?(3)?Å] between the aromatic rings link the mol-ecules into zigzag chains extending along [010].

SUBMITTER: Kim YI

PROVIDER: S-EPMC2983418 | biostudies-literature | 2010 Sep

REPOSITORIES: biostudies-literature

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[Benz-yl(2-pyridyl-methyl-idene)amine]-dichloridomercury(II).

Kim Young-Inn YI Kang Sung Kwon SK

Acta crystallographica. Section E, Structure reports online 20100911 Pt 10

The Hg(II) ion in the title complex, [HgCl(2)(C(13)H(12)N(2))], adopts a distorted tetra-hedral geometry being coordinated by two Cl anions and by two N atoms of the benz-yl(2-pyridyl-methyl-ene)amine ligand. The Cl-Hg-Cl plane is twisted at 70.1 (1)° from the mean plane of the chelate ring. In the crystal structure, inter-molecular π-π inter-actions [centroid-centroid distance = 3.793 (3) Å] between the aromatic rings link the mol-ecules into zigzag chains extending along [010]. ...[more]

PMID: 21587400

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