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2-Ethyl-6-(2-pyrid-yl)-5,6,6a,11b-tetra-hydro-7H-indeno[2,1-c]quinoline.

ABSTRACT: The title compound, C(23)H(22)N(2), was obtained using the three-component imino Diels-Alder reaction via a one-pot condensation between anilines, ?-pyridine-carboxy-aldehyde and indene using BF(3)·OEt(2) as the catalyst. The mol-ecular structure reveals the cis-form as the unique diastereoisomer. The crystal structure comprises one-dimensional zigzag ribbons connected via N-H?N hydrogen bonds. C-H?? inter-actions also occur.

SUBMITTER: Bohorquez AR

PROVIDER: S-EPMC2983536 | biostudies-literature | 2010 Feb

REPOSITORIES: biostudies-literature

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2-Ethyl-6-(2-pyrid-yl)-5,6,6a,11b-tetra-hydro-7H-indeno[2,1-c]quinoline.

Bohórquez Arnold R Romero AR Kouznetsov Vladimir V VV González Teresa T Briceño Alexander A

Acta crystallographica. Section E, Structure reports online 20100220 Pt 3

The title compound, C(23)H(22)N(2), was obtained using the three-component imino Diels-Alder reaction via a one-pot condensation between anilines, α-pyridine-carboxy-aldehyde and indene using BF(3)·OEt(2) as the catalyst. The mol-ecular structure reveals the cis-form as the unique diastereoisomer. The crystal structure comprises one-dimensional zigzag ribbons connected via N-H⋯N hydrogen bonds. C-H⋯π inter-actions also occur. ...[more]

PMID: 21580425

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