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1,5-Bis[(E)-1-(2-hydroxyphenyl)ethyl-idene]thiocarbonohydrazide mono-hydrate.

ABSTRACT: In the title compound, C(17)H(18)N(4)O(2)S·H(2)O, the thio-urea derivative is almost planar, with an r.m.s. deviation for the non-H atoms of 0.057?Å. The hydroxyl groups lie to the same side of the mol-ecule as the thione S atom, a conformation that allows the formation of intra-molecular O-H?S and O-H?N hydrogen bonds. In the crystal structure, the thio-urea and water mol-ecules self-assemble into a two-dimensional array by a combination of O(water)-H?O(hydrox-yl), N-H?O(water) and O(water)-H?S hydrogen bonds and C-H?? inter-actions.

SUBMITTER: Affan MA

PROVIDER: S-EPMC2983601 | biostudies-literature | 2010 Feb

REPOSITORIES: biostudies-literature

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1,5-Bis[(E)-1-(2-hydroxyphenyl)ethyl-idene]thiocarbonohydrazide mono-hydrate.

Affan Md Abu MA Chee Dayang N A DN Ahmad Fasihuddin B FB Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20100206 Pt 3

In the title compound, C(17)H(18)N(4)O(2)S·H(2)O, the thio-urea derivative is almost planar, with an r.m.s. deviation for the non-H atoms of 0.057 Å. The hydroxyl groups lie to the same side of the mol-ecule as the thione S atom, a conformation that allows the formation of intra-molecular O-H⋯S and O-H⋯N hydrogen bonds. In the crystal structure, the thio-urea and water mol-ecules self-assemble into a two-dimensional array by a combination of O(water)-H⋯O(hydrox-yl), N-H⋯O(water) and O(water)-H⋯S ...[more]

PMID: 21580324

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