Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

1,5-Bis(1-phenyl-ethyl-idene)thio-carbono-hydrazide.

ABSTRACT: The title mol-ecule, C(17)H(18)N(4)S, is not planar, as indicated by the dihedral angle of 27.24?(9)° between the two benzene rings. In the crystal, inter-molecular N-H?S hydrogen bonds link pairs of mol-ecules into inversion dimers.

SUBMITTER: Feng L

PROVIDER: S-EPMC3120603 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

1,5-Bis(1-phenyl-ethyl-idene)thio-carbono-hydrazide.

Feng Lei L Ji Haiwei H Wang Renliang R Ge Haiyan H Li Li L

Acta crystallographica. Section E, Structure reports online 20110525 Pt 6

The title mol-ecule, C(17)H(18)N(4)S, is not planar, as indicated by the dihedral angle of 27.24 (9)° between the two benzene rings. In the crystal, inter-molecular N-H⋯S hydrogen bonds link pairs of mol-ecules into inversion dimers. ...[more]

PMID: 21754879

Similar Datasets

1,5-Bis[(E)-cyclo-pentyl-idene]thio-carbono-hydrazide.

Project description:In the title mol-ecule, C(11)H(18)N(4)S, an intra-molecular N-H⋯N hydrogen bond [N⋯N = 2.558 (3)Å] is observed. The two cyclo-pentyl rings are disordered between two conformations in 1:1 and 2:1 ratios. In the crystal structure, weak inter-molecular N-H⋯S hydrogen bonds [N⋯S = 3.547 (3) Å] link pairs of mol-ecules into centrosymmetric dimers.

| S-EPMC2969008 | biostudies-literature

A monoclinic polymorph of (1E,5E)-1,5-bis-(2-hy-droxy-benzyl-idene)thio-carbono-hydrazide.

Project description:The title compound, C(15)H(14)N(4)O(2)S, is a derivative of thio-ureadihydrazide. In contrast to the previously reported polymorph (ortho-rhom-bic, space group Pbca, Z = 8), the current study revealed monoclinic symmetry (space group P2(1)/n, Z = 4). The mol-ecule shows non-crystallographic C(2) as well as approximate C(s) symmetry. Intra-molecular bifurcated O-H?(N,S) hydrogen bonds, are present. In the crystal, inter-molecular N-H?S hydrogen bonds and C-H?? contacts connect the mol-ecules into undulating chains along the b axis. The shortest centroid-centroid distance between two aromatic systems is 4.5285?(12)?Å.

| S-EPMC3213636 | biostudies-literature

1,5-Bis(1-phenyl-ethyl-idene)carbonohydrazide.

Project description:In the title mol-ecule, C(17)H(18)N(4)O, the two phenyl rings form a dihedral angle of 18.15?(17)°. In the crystal, pairs of inter-molecular N-H?O hydrogen bonds link the mol-ecules into centrosymmetric dimers. Weak inter-molecular C-H?O inter-actions further link the dimers into chains running along [010].

| S-EPMC3009061 | biostudies-literature

1-[1-(4-Chloro-phen-yl)ethyl-idene]carbono-hydrazide.

Project description:The mol-ecular skeleton of the title mol-ecule, C(9)H(11)ClN(4)O, is essentially planar, the dihedral angle between the ring and the and N/N/C plane being 6.7 (3)°. In the crystal, inter-molecular N-H⋯O and N-H⋯N hydrogen bonds link the mol-ecules into ribbons propagated along [010].

| S-EPMC2969952 | biostudies-literature

1,5-Bis[1-(4-bromo-phen-yl)ethyl-idene]thio-carbonohydrazide.

Project description:The asymmetric unit of the title compound, C17H16Br2N4S, contains two independent mol-ecules in which the benzene rings form dihedral angles of 20.0?(1) and 55.3?(1)°. In the crystal, a pair of N-H?S hydrogen bonds link the two different independent mol-ecules into a dimer.

| S-EPMC3648255 | biostudies-literature

1,5-Bis[1-(4-meth-oxy-phen-yl)ethyl-idene]thio-carbonohydrazide.

Project description:In the title mol-ecule, C(19)H(22)N(4)O(2)S, the two benzene rings form a dihedral angle of 9.16?(13)°. In the crystal, pairs of weak inter-molecular C-H?S hydrogen bonds link the mol-ecules into centrosymmetric dimers, which are further linked through weak C-H?O inter-actions into sheets parallel to (012).

| S-EPMC3213572 | biostudies-literature

N'-[(E)-1-Phenyl-ethyl-idene]benzo-hydrazide.

Project description:The title compound, C(15)H(14)N(2)O, crystallized with two independent mol-ecules in the asymmetric unit. Both mol-ecules are non-planar and have an E configuration with respect to the C=N bond. The dihedral angles between the two benzene rings are 11.1?(2)° in one mol-ecule and 12.40?(19)° in the other. In the crystal structure, the mol-ecules are linked by N-H?O hydrogen bonds and weak C-H?O inter-actions into infinite one-dimensional chains along [1 0 0]. The crystal structure is further stabilized by N-H?O hydrogen bonds, weak C-H?O and very weak C-H?? inter-actions.

| S-EPMC2959329 | biostudies-literature

Crystal structure of (E)-N-phenyl-N'-[1-(thio-phen-2-yl)ethyl-idene]formo-hydrazide.

Project description:In the title compound, C13H12N2OS, the planes of the thio-phene and phenyl rings are nearly perpendicular to each other, making a dihedral angle of 86.42 (12)°. In the crystal, mol-ecules are linked by C-H⋯O hydrogen bonds, forming a helical chain along the b-axis direction.

| S-EPMC4186119 | biostudies-literature

1,5-Bis(4-iso-propyl-benzyl-idene)thio-carbonohydrazide.

Project description:The title compound, C21H26N4S, was synthesized by the condensation reaction of 4-iso-propyl-benzaldehyde with thio-carbohydrazide in ethanol. The planes of the two benzene rings in the mol-ecule are inclined at 22.6?(1)°. In the crystal, pairs of inter-molecular N-H?S hydrogen bonds link the mol-ecules into inversion dimers.

| S-EPMC3884323 | biostudies-literature

1,5-Bis(4-meth-oxy-benzyl-idene)thio-carbonohydrazide methanol monosolvate.

Project description:In the title compound, C(17)H(18)N(4)O(2)S·CH(3)OH, the two benzene rings in the thio-carbonohydrazide mol-ecule form a dihedral angle of 22.42?(18)°. Pairs of N-H?S hydrogen bonds link thio-carbonohydrazide mol-ecules into centrosymmetric dimers. Methanol solvent mol-ecules serve as donors (O-H?S and O-H?N) and acceptors (N-H?O and C-H?O) of weak inter-molecular hydrogen bonds, which link further these dimers into double ribbons along the b axis.

| S-EPMC3213573 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data