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Ethyl [1-(4-bromo-phen-yl)-1-hydr-oxy-3-oxobut-yl](phen-yl)phosphinate monohydrate.

ABSTRACT: In the title hydrate, C(18)H(20)BrO(4)P·H(2)O, a staggered conformation is found when the organic mol-ecule is viewed down the central P-C bond, with the oxo and hydroxyl groups being diagonally opposite; each of the central P and C atoms has an S-configuration. The crystal structure features supra-molecular double chains along the b axis mediated by O(hydrox-yl)-H?O(oxo), O(water)-H?O(oxo), and O(water)-H?O(water) hydrogen bonds.

SUBMITTER: Samanta S

PROVIDER: S-EPMC2983684 | biostudies-literature | 2010 Feb

REPOSITORIES: biostudies-literature

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Ethyl [1-(4-bromo-phen-yl)-1-hydr-oxy-3-oxobut-yl](phen-yl)phosphinate monohydrate.

Samanta Sampak S Perera Sandun S Broker Grant A GA Zhao Cong-Gui CG Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20100210 Pt 3

In the title hydrate, C(18)H(20)BrO(4)P·H(2)O, a staggered conformation is found when the organic mol-ecule is viewed down the central P-C bond, with the oxo and hydroxyl groups being diagonally opposite; each of the central P and C atoms has an S-configuration. The crystal structure features supra-molecular double chains along the b axis mediated by O(hydrox-yl)-H⋯O(oxo), O(water)-H⋯O(oxo), and O(water)-H⋯O(water) hydrogen bonds. ...[more]

PMID: 21580337

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