Ontology highlight
ABSTRACT:
SUBMITTER: Hao L
PROVIDER: S-EPMC2983704 | biostudies-literature | 2010 Feb
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20100213 Pt 3
Crystals of the title compound, [Fe(C(8)H(7)N(3))(3)](2)[PMo(12)O(40)]·6H(2)O, prepared under hydro-thermal conditions, are isotypic with the Mn(2+) and Cd(2+) analogues. The Fe(2+) cation is in a distorted octa-hedral coordination by six N atoms from three chelating 3-(2-pyrid-yl)-1H-pyrazole ligands. The heteropoly-anion [PMo(12)O(40)](4-) is a one-electron reduced species in which two O atoms of the central PO(4) group ( symmetry) are equally disordered about an inversion centre. N-H⋯O and O- ...[more]