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Tris(morpholinium) hexa-?(3)-hydroxido-hexa-?(2)-oxido-dodeca-oxidohexa-molybdenum(VI)chromate(III) tetra-hydrate.


ABSTRACT: In the title organic-inorganic hybrid compound, (C(4)H(10)NO)(3)[H(6)CrMo(6)O(24)]·4H(2)O, the Anderson-type [H(6)CrMo(6)O(24)](3-) polyoxoanion is centrosymmetric, with the Cr(III) ion lying on an inversion center. One of the two crystallographiclly independent morpholinium cations is half-occupied. Inter-molecular N-H?O and O-H?O hydrogen bonds link the cations, polyoxoanions and uncoordinated water mol-ecules.

SUBMITTER: Yang YY 

PROVIDER: S-EPMC3120305 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

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Tris(morpholinium) hexa-μ(3)-hydroxido-hexa-μ(2)-oxido-dodeca-oxidohexa-molybdenum(VI)chromate(III) tetra-hydrate.

Yang Yan-Yan YY   Song Yu Y   Liu Li-Ye LY   Qu Xiao-Shu XS  

Acta crystallographica. Section E, Structure reports online 20110520 Pt 6


In the title organic-inorganic hybrid compound, (C(4)H(10)NO)(3)[H(6)CrMo(6)O(24)]·4H(2)O, the Anderson-type [H(6)CrMo(6)O(24)](3-) polyoxoanion is centrosymmetric, with the Cr(III) ion lying on an inversion center. One of the two crystallographiclly independent morpholinium cations is half-occupied. Inter-molecular N-H⋯O and O-H⋯O hydrogen bonds link the cations, polyoxoanions and uncoordinated water mol-ecules. ...[more]

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