Unknown

Dataset Information

0

(Z)-Ethyl 3-(2,6-diisopropyl-anilino)but-2-enoate.

ABSTRACT: The title compound, C(18)H(27)NO(2), crystallizes as the enamine form with Z geometry. The ?-enamino-ester fragment forms a dihedral angle of 87.5?(1)° with the isopropyl-phenyl frame. The structure exhibits an intra-molecular N-H?O hydrogen bond. In addition, in the crystal, mol-ecules are linked by a centrosymmetric inter-molecular N-H?O hydrogen bond.

SUBMITTER: Amezquita-Valencia M 

PROVIDER: S-EPMC2983729 | biostudies-literature | 2010 Feb

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

(Z)-Ethyl 3-(2,6-diisopropyl-anilino)but-2-enoate.

Amézquita-Valencia Manuel M   Hernández-Ortega Simón S   Suárez-Ortiz G Alejandra GA   Cabrera Armando A  

Acta crystallographica. Section E, Structure reports online 20100203 Pt 3

The title compound, C(18)H(27)NO(2), crystallizes as the enamine form with Z geometry. The β-enamino-ester fragment forms a dihedral angle of 87.5 (1)° with the isopropyl-phenyl frame. The structure exhibits an intra-molecular N-H⋯O hydrogen bond. In addition, in the crystal, mol-ecules are linked by a centrosymmetric inter-molecular N-H⋯O hydrogen bond. ...[more]

Similar Datasets

Unknown 1,3-Bis(2,6-diisopropyl-anilino)-1-phenyl-butyl-ium hexa-fluorido-phosphate.
| S-EPMC2915305 | biostudies-literature
Unknown (Z)-Ethyl 3-(2,4,6-trimethyl-anilino)but-2-enoate.
| S-EPMC2971173 | biostudies-other
Unknown Ethyl (Z)-3-(4-methyl-anilino)-2-[(4-methyl-phen-yl)carbamo-yl]prop-2-enoate.
| S-EPMC3515303 | biostudies-literature
Unknown (2Z,6Z)-N,N-Bis(2,6-diisopropyl-phen-yl)-N,N-bis-(2-methoxy-ethyl)pyridine-2,6-dicarboxamidine.
| S-EPMC2915285 | biostudies-literature
Unknown trans-Bis{1-[2-(2,6-diisopropyl-anilino)phenyl]-3-isopropyl-imidazolin-2-ylidenyl-?C}diiodidopalladium(II) benzene disolvate.
| S-EPMC3120432 | biostudies-literature
Unknown (4Z)-4-[(2,6-Diisopropyl-anilino)(phen-yl)methyl-idene]-3-methyl-1-phenyl-1H-pyrazol-5(4H)-one.
| S-EPMC3051710 | biostudies-literature
Unknown Dichlorido[(Z)-4-(2,6-diisopropyl-anilino)pent-3-en-2-one]dimethyl-tin(IV).
| S-EPMC2979832 | biostudies-other
Unknown Structural Diversity in Alkali Metal and Alkali Metal Magnesiate Chemistry of the Bulky 2,6-Diisopropyl-N-(trimethylsilyl)anilino Ligand.
| S-EPMC5096043 | biostudies-literature
Unknown (Z)-Methyl 3-(4-ethoxy-anilino)but-2-enoate.
| S-EPMC2961375 | biostudies-literature
Unknown N-(2,6-Diisopropyl-phen-yl)formamide.
| S-EPMC2960669 | biostudies-literature