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(Z)-Ethyl 3-(2,6-diisopropyl-anilino)but-2-enoate.

ABSTRACT: The title compound, C(18)H(27)NO(2), crystallizes as the enamine form with Z geometry. The ?-enamino-ester fragment forms a dihedral angle of 87.5?(1)° with the isopropyl-phenyl frame. The structure exhibits an intra-molecular N-H?O hydrogen bond. In addition, in the crystal, mol-ecules are linked by a centrosymmetric inter-molecular N-H?O hydrogen bond.

SUBMITTER: Amezquita-Valencia M

PROVIDER: S-EPMC2983729 | biostudies-literature | 2010 Feb

REPOSITORIES: biostudies-literature

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(Z)-Ethyl 3-(2,6-diisopropyl-anilino)but-2-enoate.

Amézquita-Valencia Manuel M Hernández-Ortega Simón S Suárez-Ortiz G Alejandra GA Cabrera Armando A

Acta crystallographica. Section E, Structure reports online 20100203 Pt 3

The title compound, C(18)H(27)NO(2), crystallizes as the enamine form with Z geometry. The β-enamino-ester fragment forms a dihedral angle of 87.5 (1)° with the isopropyl-phenyl frame. The structure exhibits an intra-molecular N-H⋯O hydrogen bond. In addition, in the crystal, mol-ecules are linked by a centrosymmetric inter-molecular N-H⋯O hydrogen bond. ...[more]

PMID: 21580278

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