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(E)-N'-(2,4,5-Trifluorobenzyl-idene)isonicotinohydrazide monohydrate.

ABSTRACT: In the Schiff base mol-ecule of the title compound, C(13)H(8)F(3)N(3)O·H(2)O, the benzene ring and the pyridine ring are nearly coplanar, making a dihedral angle of 6.64?(7)°. The mol-ecule exists in an E configuration with respect to the C=N double bond. In the crystal structure, mol-ecules are linked via the water mol-ecules into two-dimensional planes parallel to the ab plane through inter-molecular N-H?O, O-H?O O-H?N and C-H?O hydrogen bonds.

SUBMITTER: Naveenkumar HS

PROVIDER: S-EPMC2983744 | biostudies-literature | 2010 Feb

REPOSITORIES: biostudies-literature

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(E)-N'-(2,4,5-Trifluorobenzyl-idene)isonicotinohydrazide monohydrate.

Naveenkumar H S HS Sadikun Amirin A Ibrahim Pazilah P Yeap Chin Sing CS Fun Hoong-Kun HK

Acta crystallographica. Section E, Structure reports online 20100210 Pt 3

In the Schiff base mol-ecule of the title compound, C(13)H(8)F(3)N(3)O·H(2)O, the benzene ring and the pyridine ring are nearly coplanar, making a dihedral angle of 6.64 (7)°. The mol-ecule exists in an E configuration with respect to the C=N double bond. In the crystal structure, mol-ecules are linked via the water mol-ecules into two-dimensional planes parallel to the ab plane through inter-molecular N-H⋯O, O-H⋯O O-H⋯N and C-H⋯O hydrogen bonds. ...[more]

PMID: 21580346

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