Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

(E)-N-{2-[1-(Benzyl-imino)eth-yl]phen-yl}benzamide.

ABSTRACT: In the title compound, C(22)H(20)N(2)O, the molecular conformation is supported by an intra-molecular N-H?N hydrogen bond, resulting in an almost planar [mean deviation = 0.048?(2)?Å] S(6) ring. The dihedral angles between the central benzene ring and the imine- and amide-substituted aromatic rings are 76.6?(2) and 11.7?(2)°, respectively.

SUBMITTER: Wang CH

PROVIDER: S-EPMC2983772 | biostudies-literature | 2010 Mar

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

(E)-N-{2-[1-(Benzyl-imino)eth-yl]phen-yl}benzamide.

Wang Chao-Hsiang CH Liu Yi-Chang YC Lin Chia-Her CH Ko Bao-Tsan BT

Acta crystallographica. Section E, Structure reports online 20100303 Pt 4

In the title compound, C(22)H(20)N(2)O, the molecular conformation is supported by an intra-molecular N-H⋯N hydrogen bond, resulting in an almost planar [mean deviation = 0.048 (2) Å] S(6) ring. The dihedral angles between the central benzene ring and the imine- and amide-substituted aromatic rings are 76.6 (2) and 11.7 (2)°, respectively. ...[more]

PMID: 21580590

Similar Datasets

4-Chloro-2-((E)-{3-[1-(hydroxy-imino)eth-yl]phen-yl}imino-meth-yl)phenol.

Project description:The title compound, C(15)H(13)ClN(2)O(2), adopts an E conformation with respect to the azomethine C=N bond. The aniline and phenol rings are almost coplanar, making a dihedral angle of 3.33?(2)°. In the crystal, the mol-ecules lie about inversion centers, forming dimers that are connected by inter-molecular O-H?N hydrogen bonds, resulting in six-membered rings with graph-set motif R(2) (2)(6). In addition, there is a strong inter-molecular O-H?N hydrogen-bonding inter-action, resulting in an S(6) ring motif. Weak ?-? inter-actions between the benzene rings [centroid-centroid distance = 3.809?(1)?Å] further stabilize the crystal structure.

| S-EPMC2972112 | biostudies-literature

Bis{2-[1-(benzyl-imino)-eth-yl]phenolato}palladium(II).

Project description:In the title compound, [Pd(C(15)H(14)NO)(2)], the Pd atom lies on an inversion center and is coordinated by two ligand mol-ecules through the O and N atoms in a bidentate manner, forming a slightly distorted square-planar geometry. The dihedral angle between the two benzene rings in the ligand is 76.53 (19)°. The mol-ecular packing is stablized by C-H⋯O and C-H⋯π inter-actions.

| S-EPMC3007840 | biostudies-literature

4-[(E)-(4-Eth-oxy-phen-yl)imino-meth-yl]phenol.

Project description:In the title compound, C(15)H(15)NO(2), the dihedral angle between the benzene rings is 52.04 (5)° and the mol-ecule has an E conformation about the central C=N bond. In the crystal, mol-ecules are connected by O-H⋯N hydrogen bonds, forming zigzag chains along the b axis. The crystal packing also features weak C-H⋯O inter-actions.

| S-EPMC3435674 | biostudies-literature

2-((E)-{4-[Bis(4-eth-oxy-phen-yl)amino]-phen-yl}imino-meth-yl)phenol.

Project description:In the title Schiff base mol-ecule, C29H28N2O3, the three terminal benzene rings are twisted by 73.84 (15), 81.25 (16) and 12.1 (2)° with respect to the central benzene ring. An intra-molecular O-H⋯N hydrogen bond occurs. In the crystal, mol-ecules are linked via weak C-H⋯π inter-actions into a three-dimensional supra-molecular architecture.

| S-EPMC3998452 | biostudies-literature

(E)-2-Eth-oxy-6-[(4-ethoxy-phen-yl)imino-meth-yl]phenol.

Project description:In the asymmetric unit of the title compound, C(17)H(19)NO(3), there are three independent mol-ecules, which are align nearly parallel to each other and adopt the phenol-imine tautomeric form. In each mol-ecule, an intra-molecular O-H⋯N hydrogen bond results in the formation of an S(6) ring motif. The dihedral angles between the aromatic rings in the three independent mol-ecules are 13.55 (2), 21.24 (2) and 46.26 (1)°. C-H⋯π inter-actions are also observed in the crystal structure.

| S-EPMC2983578 | biostudies-literature

2-(Thio-phen-2-yl)-N-(4-{(E)-[2-(thio-phen-2-yl)eth-yl]imino-meth-yl}benzyl-idene)ethanamine.

Project description:In the crystal of the centrosymmetric title compound, C(20)H(20)N(2)S(2), mol-ecules are linked by head-to-tail C-H?N hydrogen bonds, resulting in chains extending along the a axis. Three additional C-H?? inter-molecular inter-actions give rise to a herringbone packing motif which extends along the c axis. The C-H?N inter-actions provide links between the sheets.

| S-EPMC3099871 | biostudies-other

2,5-Bis{[(-)-(S)-1-(4-bromo-phen-yl)eth-yl]imino-meth-yl}thio-phene.

Project description:The title compound, C22H20Br2N2S, was synthesized under solvent-free conditions. The mol-ecule shows crystallographic C 2 symmetry, with the S atom of the central thio-phene ring lying on a twofold rotation axis. Furthermore, as a consequence of the (S,S) stereochemistry, the mol-ecule has a twisted conformation. The dihedral angle between the thio-phene and benzene rings is 72.7 (2)° and that between the two benzene rings is 55.9 (2)°. In the crystal, mol-ecules are arranged in a chevron-like pattern, without any significant inter-molecular inter-actions.

| S-EPMC3998402 | biostudies-literature

2-[1-({2-[1-(2-Hy-droxy-5-{[meth-yl(phen-yl)amino]-meth-yl}phen-yl)ethyl-idene-amino]-eth-yl}imino)-eth-yl]-4-{[meth-yl(phen-yl)amino]-meth-yl}phenol.

Project description:Mol-ecules of the title compound, C(34)H(38)N(4)O(2), lie across crystallographic inversion centres. The crystal packing can be described by alternating zigzag chains along the c axis in which the molecules are linked by van der Waals interactions. There is an intra-molecular O-H⋯N hydrogen bond and the two benzene rings in the asymmetric unit make a dihedral angle of 79.81 (6)°.

| S-EPMC3344659 | biostudies-literature

1-[1-(Hydroxy-imino)eth-yl]-N-(2-methoxy-phen-yl)cyclo-propane-carboxamide.

Project description:The title compound, C(13)H(16)N(2)O(3), adopts an E configuration with respect to the C=N bond and an intra-molecular N-H?N hydrogen bond results in the formation of a six-membered ring. In the crystal, inter-molecular O-H?O hydrogen bonds link the mol-ecules into a chain propagating along the b axis. Very weak ?-? stacking inter-actions [centroid-centroid distance = 4.18?(2)?Å] may further consolidate the packing, forming a two-dimensional supra-molecular network.

| S-EPMC2969475 | biostudies-literature

5-Diethyl-amino-2-[(E)-(4-eth-oxy-phen-yl)imino-meth-yl]phenol.

Project description:The title compound, C(19)H(24)N(2)O(2), adopts the phenol-imine tautomeric form. An intra-molecular O-H⋯N hydrogen bond results in the formation of a six-membered ring. The aromatic rings are oriented at a dihedral angle of 17.33 (16)°. Inter-molecular C-H⋯π inter-actions occur in the crystal.

| S-EPMC3051950 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data